ALBERT

Notes: Abstract Within the volcanic sequence of the twin volcanoes of Lyttelton and Akaroa, Banks Peninsula, New Zealand a number of different magma series have been distinguished. An early series of hawaiites (McQueens Valley Formation) was erupted about 32 m.y. ago and is of transitional or mildly tholeiitic chemistry. Stratigraphically above the McQueens Valley Formation, but unconformably overlain by the main volcanic dome sequence, is a unit of rhyolite (Gebbies Pass Rhyolites) which is not directly related to the earlier or later basaltic volcanism. The rhyolite was probably formed during intracrustal melting which was related to the rise of basaltic magma into the crust. Between 12 and 9.7 m.y. a large volcanic dome, composed mainly of hawaiite, was built at Lyttelton. Dykes, which intrude the Lyttelton volcanic sequence, range in composition from basalt to trachyte. Late, mildly alkalic, basaltic flank flows (7.5−5.8 m.y.) occur in several areas and they, and the differentiated rocks of the dyke swarm can be related by a crystal fractionation model which has been quantitatively tested. Following construction of the Lyttelton dome a second larger dome was built at Akaroa between 9 and 7.5 m.y. The rocks of the Akaroa Volcano are principally hawaiites but rocks ranging in composition through to trachyte also occur. The differentiated rocks of the Akaroa volcano have derived from the basaltic rocks by a crystal fractionation controlled process, operating during ascent through the crust. None of the Banks Peninsula basalts appear to have derived from primitive (pyrolitic) mantle material, but progressive changes in the chemistry of the basalts with time implies that the mantle source regions were evolving geochemically as partial melting proceeded. Later lavas tend to be more alkalic and to have lower MgO/FeO ratios than earlier lavas. The volcanic rocks of the Banks Peninsula volcanoes were derived by fractional removal of olivine, plagioclase, clinopyroxene, magnetite and apatite from ascending basaltic magma batches. Variations between the suites reflect differences between the parental magma batches.

Notes: Abstract New major and trace element analyses are presented for 7 kaersutites from basic alkaline rocks. K/Rb ratios lie between 1209 and 4276. Rb is low, averaging 6 ppm. Sr ranges from 532 to 1060 ppm and Ba from 181 to 701 ppm. Zr averages 109 ppm, Nb 44 ppm and V 390 ppm. There is a moderate enrichment in light REE. Zn correlates with FeO + Fe2O3 but the concentrations of Ni, Co, Cr, Cu and Pb are variable. Large variations in trace element concentration in kaersutites reflect only small variations in the melt when the distribution coefficient for a given element strongly favours the amphibole. Kaersutite is significant in the petrogenesis of alkaline rocks as a possible accessory phase in the upper mantle source regions, and as an important phase in the fractionation of basic alkaline liquids over a wide range of pressures.

Notes: Abstract The Longwoods Complex of Southland, New Zealand is part of an extensive terrane consisting of intrusives, volcanics, and sediments, which outcrops in the southern and north-western portions of the South Island. This terrane represents a volcanic arc which was active from Permian to Jurassic times (Grindley, 1958; Challis, 1968, 1969; Coombs et al., 1976). Between Pahia Point and Oraka Point on the southern coast of the South Island a section across the Longwoods Complex is well exposed and intrusives ranging in composition from ultrabasic cumulate rock, high-Al gabbro and gabbroic diorite to quartz diorite and granite outcrop. Two models have been considered for the origin of the rocks of the Pahia Point-Oraka Point section: (a) the rocks constitute one suite, the members of which are related by a crystal fractionation process; (b) the rocks constitute two suites which are not directly related. The ultrabasic rocks, and quartz diorites are complementary and are derived from a high-Al gabbro parent by crystal fractionation involving pyroxene, olivine, plagioclase and hornblende, but considerations of viscosity and the geochemistry of the granite preclude derivation of the high-Si rocks by continuation of the crystal fractionation model. Furthermore, the quartz-diorites are of two types: xenolith bearing foliated quartz-diorites and xenolith deficient unfoliated types. The latter rock type appears to group with the gabbros on variation diagrams and partitioning of Ti between mica and amphibole supports the view that two distinct suites of rocks are involved: (a) a suite derived by fractional crystallization from a high-Al gabbro parent and consisting of cumulate ultramafic rocks, high-Al gabbro, gabbroic diorite and quartz-diorite; (b) a suite of foliated quartz diorites, formed by partial melting of lower crustal igneous rocks. The xenoliths in the foliated quartz-diorites represent modified residue left after partial melting. Melt and residue have unmixed to varying degrees during diapiric rise and a range of compositions has resulted. The association of the two suites is tectonic. Gabbroic melts are generated in the lithosphere during plate subduction beneath a continental margin and rise of these melts into the lower continental crust results in partial melting and generation of quartz-diorite magmas.

Notes: Abstract Major and trace element data and mineral chemical data indicate that the range in rock types making up the Dunedin volcano has developed by crystal fractionation processes acting upon mantle derived basaltic magmas at various levels in the crust and upper mantle. A diversity among parental materials and the operation of the fractionation process at varying levels in the crust and mantle under varying conditions of pH2O have resulted in a diverse series of overlapping fractionation trends. ‘End member’ series are: basalt-hawaiite-mugearite-benmoreite; basanite-nepheline hawaiitenepheline mugearite-nepheline benmoreite; moderately potassic variants on these series. The phonolitic rocks of the volcano are low pressure differentiates derived by fractional crystallization, involving feldspar, as end member products in all the series outlined above. Quartz normative trachytes of the volcano appear to be differentiates from a distinct saturated or oversaturated magma series of different strontium isotopic and trace element characteristics from the undersaturated magma series.

Notes: Abstract Four muscovite-biotite granites from the Western Metamorphic Belt of South-eastern Australia have rare earth element patterns characterized by: (i) light rare earth element enrichment; (ii) slight Eu depletion; (iii) varying degrees of heavy rare earth element depletion. The rare earth element and major element chemistry of three of these muscovite-biotite granites (the Koetong, Lockharts and Yabba Granites) can be approximated very closely by a model involving 20% partial melting of an ultrametamorphosed pelitic sediment and contamination of this minimum melt by the residual material left after melting, in the ratio 60% melt: 40% residue. Granitoids can be very largely solid material at the time of emplacement. The other muscovite-biotite granite studied (the Hawksview Granite) has major and trace element characteristics which distinguish if from the other three granitoids and these differences are attributed to variations in source material at the site of melt generation. The rare earth element and major element chemistry of a garnet-cordierite gneiss from the Western Metamorphic Belt can be modelled assuming 5% partial melting of a pelitic metamorphic rock and contamination of the minimum melt by the residue in the ratio 30% melt: 70% residue. Separated granitic and biotitic portions of a migmatite from the Western Metamorphic Belt have rare earth element characteristics which are inconsistent with a simple partial-melting model, but it is suggested that re-equilibration following, or during, separation of the vein material could obscure the process by which the vein of the migmatite developed. It is however certain that the vein developed in situ from a pelitic meta-sediment leaving the biotite rich selvage, without the introduction of material from an external source. Leucogranites which crop out to the east of the Western Metamorphic Belt are high level intrusions of highly fractionated granitic melt. Their Sr isotopic characteristics and features of their major and trace element chemistry suggest that they derive from an igneous source and are not directly related to the granites and gneisses to the west.

Notes: Abstract Active spreading ridges in the North Fiji Basin range from well-developed stable ridges where largescale mantle upwelling is in progress to proto-ridges where spreading is incipient. South of 17°S, where the central ridge of the North Fiji Basin has a bathymetric profile normally expected of a fast-spreading, steadystate mid-ocean ridge, basalts are evolved N-type MORBs. North of 17°S, where the central ridge is propagating northward into old North Fiji Basin crust and spreading is in the initial stages, two types of basalt have been recovered: N-type MORBs from this northern arm of the central ridge are believed to be samples of older North Fiji Basin crust; basalts with transitional alkalic chemistry (up to 0.5% Ne in the Norm) and characterized by strong relative enrichments in Rb, Ba, K, Nb, La, Ce, Sr, P, Zr, and Ti are believed to be associated with incipient rifting. Among the latter group are compositions that are intermediate between transitional alkalic types and MORBs and these are geochemically similar to the back-arc basin (BABB) magma type defined by Sinton and Fryer (1987) from a study of Mariana back arc basin basalts. Dredges along the South Pandora Ridge, a transform zone characterized by short spreading segments, are dominated by basalts that are enriched in large-ion lithophile and high field strength minor and trace elements and compositions range from types resembling ocean island tholeiites to transitional alkalic varieties. Basalts from Rotuma are regarded as alkalic end-members of the South Pandora Ridge magmatic spectrum. In areas of the North Fiji Basin where relatively fast spreading must be accompanied by largescale asthenospheric upwelling, depleted (N-type) MORBs dominate, whereas in areas of slow mantle upwelling, or where some other tectonic effect (e.g. a transform fault) causes a transient thermal disturbance within the lithosphere or upper asthenosphere, enriched (alkalic) magmas either dominate or make a significant and noticeable contribution to the overall chemical characteristics of basalts being erupted. The MORBs have a depleted asthenospheric source, and the alkalic component is believed to derive from an enriched lithospheric or shallow asthenospheric source. The BABB magma type may simply be part of the spectrum of mixed magmas that can occur in the transitional tectonic settings represented by the early development of most back-arc basins.

Notes: Abstract A variety of alkaline lavas from the Dunedin Volcano have been analyzed for the rare earth elements (REE) La-Yb. The compositions analyzed were: basalt-hawaiite-mugearite-benmoreite; basanite, nepheline hawaiite, nepheline trachyandesite and nepheline benmoreite; trachyte; phonolite. The series from basalt to mugearite shows continuous enrichment in the REE, consistent with a crystal fractionation model involving removal of olivine and clinopyroxene. From mugearite to benmoreite there is a depletion in the REE which is explained by the appearance of apatite as a liquidus phase. The chondrite normalized REE patterns for the phonolites are characterized by strong enrichment and fractionation coupled with a sharp depletion in Eu. Removal of plagioclase from benmoreite magma is suggested for the derivation of the phonolites. The series basanite-nepheline hawaiite, and basanite-nepheline hawaiite-nepheline benmoreite appear to be high pH2O analogues of the series basalt-ben-moreite, with enrichment of the REE being achieved by removal of clinopyroxene, kaersutite and olivine. Compared with other lavas the trachyte has low REE abundances and is characterized by a striking positive Eu anomaly.

Notes: Abstract The isotopic composition of strontium has been determined for samples from the alkaline lavas of the Dunedin Volcano covering the range basalt, basanite, intermediate compositions, phonolite and quartz normative trachyte. The basaltic, intermediate and phonolitic rocks appear to be comagmatic and have similar low initial Sr87/Sr86 ratios around 0.7030, comparable with those of other alkaline provinces. The quartz normative trachytes have initial ratios significantly higher than those of the other rocks (0.7040) although their age is comparable. Contamination by sea water or crustal material could explain the higher initial ratios of the trachytes but it does not account for important features of their chemistry. It is suggested that the trachytes formed by partial melting involving an alkali feldspar-rich portion of older igneous rocks. Rb-Sr ages obtained are comparable with published K-Ar dates. The Rb-Sr age for the trachytes is 14.± 7 m.y. and the other alkali-enriched rocks give ages ranging within the limits of 14.4 to 12.0 m.y.

Notes: Abstract The first samples of volcanic basement recovered from the Kerguelen Plateau are Lower Cretaceous transitional tholeiites. Isotope and incompatible element abundance ratios for these rocks are similar to ocean island basalts from the southern hemisphere Dupal anomaly region, and geochemical, geological and geophysical data are consistent with volcanic activity associated with a mantle plume. A reconstruction of plate motions suggests that the Kerguelen Plateau formed above a mantle plume in the interval 118-95 Ma, during the opening of the Indian Ocean between India and Australia-Antarctica. This plume was the source of other plateaus and ridges of the eastern Indian Ocean and possibly the Bunbury Basalt of southwestern Australia, and is now beneath Heard Island.

Notes: Abstract Volcanic rocks collected from the Solomon Sea Basin are mostly ferrobasalt lavas similar to evolved MORB; an exception is a single sample of basaltic crystal tuff invaded by later basalt. The rocks contain labradorite, aluminous diopsidic augite, and titanomagnetite, with olivine and pigconite in the more vitrophyric samples, and segregation vesicles in some. Cobbles dredged from Gudaraba Canyon, south of the Solomon Sea Basin, include both MORB-like glassy lava and K-metasomatised basalt and andesite(?). Two small pieces of volcanic glass from the southern Bismarck Sea are more primitive MOR-type basalts.