ISSN:
1022-1352
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The synthesis of relatively high molar mass telechelic poly(chloroethyl vinyl ether)s (PCEVE) via bifunctional initiation of the “living” cationic polymerization of CEVE was examined in the absence and in the presence of various proton traps. In the absence of a proton trap, a monofunctional initiation involving hydrogen iodide (HI), formed by partial hydrolysis of trimethylsilyl iodide (TMSI) by adventitious water, occurred concurrently to the main bifunctional process. The addition of sterically hindered aromatic amines leads to complete inhibition of the polymerization due to the formation of a complex between the aromatic amines and ZnCl2. In the presence of trialkylaluminium as HI trapping agent, monofunctional initiation is totally suppressed and a clean bifunctional polymerization takes place. Telechelic PCEVE of DPn up to 300 with narrow molar mass distribution were synthesized. However, in the presence of these additives, a slow ligand exchange between AIR3 and ZnCl2 takes place, decreasing the rate of polymerization. For polymers with high DPn (〉300), the increasing amount of trialkylaluminium required to totally suppress the formation of monofunctional polymer results in a chain coupling process during the deactivation step. This reaction limits the clean synthesis of high molar mass bifunctional PCEVE.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1996.021970822
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