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The preparation of 1,4-dicarbonyl, 4-oxo nitrile, furan, and pyrrole monomers (1980)

Ponticello, I. S. ; Pastor, P. C.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 2293-2306

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Treatment of cyclopentadiene-blocked acrolein with α,β-unsaturated ketones, esters, and nitriles in the presence of a thiazoliurn salt under basic conditions led to a simple method for the preparation of acetonylmethyl Vinyl ketone, 2-carboxymethylethyl vinyl ketone, and 2-cyanoethyl vinyl ketone. In addition, the cyclopentadiene-blocked acetonylmethyl vinyl Ketone was converted to heterocyclic furan and pyrrole monomers.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1980.170180723

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