ISSN:
1572-8927
Keywords:
Solubility of nonpolar gases
;
2,2,2-trifluoroethanol
;
Lennard-Jones (6–12) potential
;
scaled particle theory
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Solubility measurements of several nonpolar gases (He, Ne, Ar, Kr, Xe, H2, N2, CH4, C2H4, C2H6, CF4, SF6, and CO2) in 2,2,2-trifluoroethanol at 25°C and 101.33 kPa partial pressure of gas are reported. Gibbs energy for the solution process at 25°C is evaluated from the experimental values of the solubility of gases expressed as mole fraction. Lennard-Jones 6–12 pair potential parameters for 2,2,2-trifluoroethanol are estimated by using the scaled particle theory (SPT); and experimental solubilities are compared with those calculated from the values of these parameters through the SPT model.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00973087
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