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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 71 (2000), S. 3846-3852 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The development and implementation of an all-optical technique for measuring thermal transport properties of materials at high pressure in a gem anvil cell are reported. Thermal transport properties are determined by propagating a thermal wave in a material subjected to high pressures, and measuring the temperature as a function of time using an optical sensor embedded downstream in the material. Optical beams are used to deposit energy and to measure the sensor temperature and replace the resistive heat source and the thermocouples of previous methods. This overcomes the problems introduced with pressure-induced resistance changes and the spatial limitations inherent in previous high-pressure experimentation. Consistent with the heat conduction equation, the material's specific heat, thermal conductivity, and thermal diffusivity (κ) determine the sensor's temperature rise and its temporal profile. The all-optical technique described focuses on room-temperature thermal properties but can easily be applied to a wide temperature range (77–600 K). Measurements of thermal transport properties at pressure up to 2.0 GPa are reported, although extension to much higher pressures are feasible. The thermal properties of NaCl, a commonly used material for high-pressure experiments are measured and shown to be consistent with those obtained using the traditional methods.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 3598-3601 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report Raman scattering and resistance measurements on a YBa2Cu3O7−δ film in which δ is varied by repeated annealing in oxygen or argon. As oxygen is removed, the resistance rises, the transition moves to lower temperature and broadens, and "forbidden'' Raman modes are observed. Group theory, the Raman activity of another oxygen rich (δ∼0) film of different orientation, and comparison with results on single crystals allow us to assign each Raman phonon. We hence demonstrate that several "forbidden'' Raman peaks are associated with depletion of oxygen chain sites. Our results establish that the oxygen concentration δ, and hence the superconducting properties, can be varied reversibly by reannealing in oxygen or argon with the Raman spectra providing a useful microscopic probe of the lattice.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 445-448 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Evidence for the prominent role of atypical reactions, and enhanced vaporization arising from resonant optical absorption of the exciting beam, in the pulsed-laser heating of thin films is presented. Time-resolved emission of Al and the reaction product AlO are monitored in the laser vaporization of Al films in air. Optical emission is observed up to 200 microseconds after an 8 μs heating pulse, indicative of long chemical lifetimes. Furthermore, increased emission from both Al and AlO up to 100 μs after the heating pulse, are observed when the laser wavelength is tuned to resonance with AlO transitions. Since the electronic resonance with the reaction product AlO affects the subsequent emission of Al, these measurements underscore the importance of physical and chemical processes peculiar to laser-induced vaporization, and ablation. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 4522-4529 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 684-686 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The measurement of the temporal profile of the pressure in a shock wave propagating underwater and interacting with a nearby metal plate is presented. Pressures are deduced from the time-resolved fluorescence of a submillimeter ruby crystal mounted on an optical fiber tip. The measured pressures agree with finite-element code predictions, which model the production and propagation of the shock wave. These measurements are useful to evaluate shock-induced phenomena that are strongly dependent on the temporal profile of a shock wave, in small-scale testing, and in substantiating finite-element code predictions. © 2000 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 2460-2462 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Experiments probing the dynamics of a thermal wave in a material compressed at static high pressures are presented. The method involves launching a thermal wave in a sample compressed in an anvil cell and monitoring the temporal profile of temperature at a fixed point downstream. A pulsed laser incident on a metal foil provides the thermal wave, while fluorescence from a small ruby sphere yields the time-resolved temperature. Results from compressed NaCl show that temperature rises quickly and decays much more slowly, consistent with the expected heat flow. This temporal profile evaluated with a numerical solution of the heat-conduction equation or an analytical approximation provides values for thermal conductivity, thermal diffusivity, and heat capacity at pressures to 1.7 GPa. © 2000 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 6662-6669 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on the use of time-resolved Raman scattering data to determine temperatures in liquid carbon tetrachloride shocked by step-wise loading to a peak pressure of 12 GPa. Changes in our previously reported experimental configuration have resulted in a significant improvement in the signal-to-noise ratio in the data and permitted us to analyze the stokes and antistokes intensities for more than one vibrational mode (314 and 460 cm−1 modes). Hence, better precision can be obtained for shock temperatures on the nanosecond time scales. Temperatures are reported in the 500–1000 K range with an experimental precision of approximately 8%–10%. Our data show that the equation of state for carbon tetrachloride reported in the literature provides temperature values that are significantly lower than the measured values. Various aspects of using Raman scattering data for determination of shock temperatures are discussed. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 70 (1997), S. 967-969 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The use of time-resolved Raman scattering measurements to determine temperature in shocked materials is demonstrated. Experimental data were obtained by monitoring the stokes and antistokes intensities of the 460 cm−1 vibrational mode, at 50 ns intervals, in liquid carbon tetrachloride shocked to 12 GPa using step wise loading. The ratio of antistokes to stokes intensities changes in a pronounced manner with increasing pressure. Procedures to obtain precise temperatures are outlined, and improvements for future work are indicated. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Publication Date: 2000-04-24
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 10
    Publication Date: 2006-06-01
    Print ISSN: 0034-6748
    Electronic ISSN: 1089-7623
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
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