ISSN:
0009-2940
Schlagwort(e):
Decaborane
;
1-Phosphabutin, 3,3-dimethyl
;
Bis(decaboranyl)methane
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Reaction of Decaborane with the Phosphaalkyne PC tBuThe borane B10H12(SMe2)2 (1) reacts with the phosphaalkyne P°CtBu to form the product [B10H11(SMe2)][C(tBu)-PH](B10H12) (2), in which two B10 units are linked by a HP-CtBu bridge. The B10 unit B is simply bound to the bridge C atom, whereas the B10 unit A is bound to both bridging atoms, P and C, by atom B6 and, moreover, to the P atom by atom B5. The solvate complex 2 · CH2Cl2 crystallizes in the space group P¯.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19941270115
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