ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The reaction of 1,1-dimethyl-l-silaacenaphthene with chromium carbonyl complexes L3Cr(CO)3, where L=CO, NH3, and C6H5N leads to a mixture of isomeric complexes differing in the position of the Cr(CQ)3 group. 2. The interconversion of these isomeric chromium tricarbonyl complexes occurs in benzene, toluene, cyclohexane and decane at from 80 to 115°C due to reversible transfer of the Cr(CO)3 group between the six-membered rings. The thermodynamic and kinetic parameters of this isomerization were established.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00957539
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