Publication Date:
2014-12-14
Description:
In the title compound, C36H44O10·C6H6, the dioxolane ring adopts an envelope conformation with the C atom bonded to the H atom as the flap, while the cyclohexene and cyclohexane rings are in half-chair and chair conformations, respectively. In the crystal, a pair of O—H...O hydrogen bonds with an R22(26) graph-set motif connect the benzoate molecules into an inversion dimer. The dimers are linked by a weak C—H...O interaction into a tape structure along [01-1]. The benzene molecule links the tapes through C—H...O and C—H...π interactions, forming a sheet parallel to (100).
Keywords:
crystal structurehydrogen bondstaxane skeletonpaclitaxel
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences
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