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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Advances in science and technology Vol. 45 (Oct. 2006), p. 173-177 
    ISSN: 1662-0356
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Natural Sciences in General , Technology
    Notes: The corrosion behavior of Si3N4, SiC, mullite, alumina and sapphire was investigated insupercritical water at 450 ºC and 45MPa for 2 to 50h. Corrosion resistance for the ceramics was asfollows in the order; Si3N4 〈 SiC 〈 mullite 〈 alumina 〈 sapphire. Pitting corrosion with formation ofamorphous layer and intergranular corrosion due to dissolution of additives were observed inPLS-Si3N4 and PLS-SiC, respectively. The corrosion behavior of mullite was characterized bydissolution of SiO2 and formation of boehmite residue layer. High purity alumina ceramics showedthe highest corrosion resistance in the ceramics. Intergranular corrosion proceeded in the aluminaceramics and its corrosion rate was strongly dependent on the impurity content
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hydrothermal corrosion and strength degradation of aluminum nitride (AlN) ceramics were investigated. The weight gain in AlN ceramics after corrosion occurred because of the formation of boehmite. The reaction kinetics of AlN with water were diffusion controlled through the boehmite product layer. At 180°C, immersion in water caused no strength degradation, and water vapor caused a 20% strength degradation. At 300°C, immersion in water caused a 20% strength degradation, and water vapor caused a 30% strength degradation.
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The corrosion behavior and strength degradation of alumina ceramics with 99%, 99.9%, and 99.99% Al2O3 were studied in water at 300°C and 8.6 MPa for 1 to 10 d. The weight loss in alumina ceramics was mainly attributed to the dissolution of SiO2 and Na2O grain-boundary impurities. Intergranular corrosion proceeded in the alumina ceramics by preferential attack at the grain boundaries. The extent of the strength reduction for corroded alumina ceramics was related to the impurity level in the alumina ceramics.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 9 (1990), S. 1319-1321 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 3648-3652 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Nb100−x B x alloy films were prepared by the r.f.-sputtering method in the chemical composition range of 30 ≦x ≦ 76. Nb100−x B x (30 ≦x ≦ 54) films consisted of the amorphous state, and NbB2 crystal phase was observed on Nb100−xBx (67 ≦x ≦ 76) films. A remarkable preferred orientation with the (001) plane of NbB2 in parallel to the film surface was observed on Nb33B67 film. d.c. electrical conductivity of Nb100−xBx (30 ≦x ≦ 76) films decreased with increasing content of boron in the range from 7.3×103 to 7.6 ×102Ω−1cm−1. Micro-Vickers hardness of Nb100−x B x (30 ≦x ≦ 76) films exhibited the values of 1070 to 2060 kg mm2.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 3648-3652 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Nb100−x B x alloy films were prepared by the r.f.-sputtering method in the chemical composition range of 30 ≦x ≦ 76. Nb100−x B x (30 ≦x ≦ 54) films consisted of the amorphous state, and NbB2 crystal phase was observed on Nb100−xBx (67 ≦x ≦ 76) films. A remarkable preferred orientation with the (001) plane of NbB2 in parallel to the film surface was observed on Nb33B67 film. d.c. electrical conductivity of Nb100−xBx (30 ≦x ≦ 76) films decreased with increasing content of boron in the range from 7.3×103 to 7.6 ×102Ω−1cm−1. Micro-Vickers hardness of Nb100−x B x (30 ≦x ≦ 76) films exhibited the values of 1070 to 2060 kg mm2.
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  • 7
    ISSN: 1072-8368
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Medicine
    Notes: [Auszug] The crystal structure of a pepstatin-insensitive carboxyl proteinase from Pseudomonas sp. 101 (PSCP) has been solved by single-wavelength anomalous diffraction using the absorption peak of bromide anions. Structures of the uninhibited enzyme and of complexes with an inhibitor that was either ...
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 22 (1987), S. 2729-2733 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Co-N films in the wide compositional range can be prepared by reactive sputtering. Co-N sputtered films consist of one or two phases, such as CoN, Co2N, Co3N, Co4N and α-Co. Co4N phase with a cubic unit cell is observed, and its lattice constant isa = 0.3586 nm. The preferred orientation is observed on the Co-N films, CoN (200) plane, Co4N (1 1 1) plane and α-Co (002) plane parallel to the film surface, respectively. Saturation magnetization σs of Co-N sputtered film decreases from 160 to 1.7 e.m.u. g−1 with increasing content of N from 0 to 21.7 at%, and coercive forceI H c is the range of 43 to 5000e at room temperature.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 25 (1990), S. 2557-2561 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Fe-N films over a wide compositional range have been prepared by the reactive sputtering method. Fe-N sputtered films were composed of a single or two phases such asζ-Fe2N,ε-Fe3.02N,γ′-Fe3.82N,γ′-Fe4N andα-Fe; however, an unknown phase was observed at a higher nitrogen pressure. A remarkable preferred orientation of theε-Fe3.02N (110) plane parallel to the film surface was observed. The Curie temperature of the sputtered γ′-Fe3.82N sample was 490° C, which was almost the same as that ofγ′-Fe4N prepared by metal nitriding. The saturation magnetization,σ s, of the sputtered Fe-N samples decreased from 151.8 to 42.4 e.m.u.g−1 with increasing nitrogen content from 7.94 to 24.87 at%, and its coercive force,1 H c was found to lie in the range 150 to 600 Oe in the powder form at room temperature.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 53 (1997), S. 387-390 
    ISSN: 0006-3592
    Keywords: enzymatic synthesis ; peptide synthesis ; Vibrio ; protease ; thermolysin ; organic solvent ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Condensation of Cbz-Asp and PheOMe catalyzed by a neutral protease from Vibrio sp. T1800 (Vimelysin: VLN) was studied. VLN showed a relatively higher catalytic activity of condensation and an apparently larger yield after 3 h or 24 h, in comparison with thermolysin (TLN), especially at lower pH and temperatures.VLN showed higher solvent-tolerance than TLN. TLhe apparent highest yield (25%) was obtained in 30% DMSO by using VLN; under similar conditions, TLN gave only about a half of this value. The rate of the condensation reaction per mole of enzyme (v/[E]o) in DMSO 50% at 37°C and pH 6.5 was 0.16 s-1 for VLN and 0.047 s-1 for TLN. In 30% ethanol VLN showed more than three-fold peptide yield than TLN after 5 h reaction. © 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 53: 387-390, 1997.
    Additional Material: 3 Ill.
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