ISSN:
1573-9171
Keywords:
cathodic electrolysis
;
stereoselective alkylation of phosphite anion
;
2-benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinane
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Benzylation ofcis2-hydro-2-oxo-4-methyl-1,3,2-dioxaphosphorinane in the electro-chemical version of the Michaelis-Becker reaction occurs stereospecifically with retention of the stereochemistry of the hydrophosphoryl center and affords stereochemically pure 2-benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinane (yield 60–70 %). The structure of this compound was determined by X-ray diffraction analysis. The mechanism of the process was discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01433988
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