ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The mass spectra of alkanesulfonyl chlorides can be rationalized by loss of a chlorine atom from the molecular ion, followed by loss of SO2 with concomitant alkyl cation formation. The mass spectra of two α-mesyl sulfonyl chlorides exhibit a new fragmentation process in which the chlorine atom initially attached to sulfur migrates to the α-carbon atom with loss of SO2, thereby resulting in retention of chlorine in the alkyl cation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210091112
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