ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions. 2. Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00953288
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