ISSN:
0930-7516
Keywords:
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The gas-phase hydrogenation of buta-1,3-diene to but-1-ene, trans- and cis-but-2-ene and butane has been performed over 0.5% Pd/γ-Al2O3 catalyst. The reaction has been investigated at atmospheric pressure and 0°C over a wide range of conversions. The kinetic model based on the present day knowledge of reaction mechanism has been advanced. The parameters of the kinetic model have been estimated through statistical data fitting. The kinetic model provides a fairly good description of selectivity in the whole range of conversions.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/ceat.270200211
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