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  • 1
    Publication Date: 1981-01-01
    Description: Recent experimental work has suggested that the relative fractionation of 14C to 13C may differ from the accepted value of b = 2. In order to explore the implications of this possibility, the standard formulae for correcting radiocarbon dates for fractionation effects are rederived, but without making any of the usual assumptions or approximations. A generalized dating equation is derived (where ASN and AON are normalized sample and standard activities, β is a factor which reflects changes in atmospheric 13C and 14C content, {RST(o)/RST}b accounts for post-depositional changes in sample 13C ratio, and tcal is calendar age in years before ad 1950. The errors in calculated ages which might arise from different b values are estimated and shown to be small relative to other dating uncertainties. The effect of b ≠ 2 may be important in the calibration of radiocarbon dates using tree-ring samples of known age. A theoretical analysis suggests that b ≠ 2 effects may result in a correlation between age anomaly (ie, the difference between radiocarbon age and calendar age) and sample 13C data. However, an analysis of published data reveals no meaningful correlation. This result, while not eliminating the possibility that b ≠ 2, highlights its unimportance even in this high-precision application of radiocarbon dating.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 2
    Publication Date: 1983-01-01
    Description: The Meade thrust, in southeastern Idaho, is a major element of the Western Overthrust Belt. The allochthon is of geo-economic importance both as a potential hydrothermal area and as the principal mining area within the Western Phosphate Field. To assist in the development of these two resources, an understanding of the regional ground-water circulation was sought. Geologic and hydrologic data from boreholes in this area are virtually nonexistent. Waterwell development in the area has not occurred because of the abundance of springs and only a few hydrocarbon exploration boreholes have been drilled. Thus, the problem lends itself to evaluation by isotope hydrologic and geochemical methods. Ten springs from within the thrust block and around its periphery were sampled for major ions, 2H/18O, and 14C/13C analysis. Data from these analyses and from field geologic evidence have identified two distinct flow regimes within the Meade thrust allochthon. Shallow flow systems lie above the impermeable Phosphoria Formation, usually within a few hundred meters of the surface. Most of the spring waters from this system are recent and cool. In all cases, they have mean subsurface residence times of less than a few hundred years. The deeper flow systems which lie below the Phosphoria formation are hydraulically isolated from the shallow system. Warm waters from these springs have 14C contents suggesting mean ground-water residence times on the order of 15,000 years. Although these waters could have circulated to as deep as 1900m, 2H/18O results show that high temperatures were never reached. There is no evidence to suggest that water from beneath the Meade thrust has contributed to the circulation in the allochthon.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 3
    Publication Date: 1980-01-01
    Description: The use of materials having high levels of 14C activity (up to 113 times the activity of modern carbon) enabled a quantitative analysis of the magnitude and sites of memory occurring in the routine synthesis of benzene, via lithium carbide, for radiocarbon dating. Memory may be expressed as the percentage or fractional contribution of carbon from sources other than the original sample in this synthesis. Although tritium and radon contamination have also been found, the major site of memory was the inner surface of the stainless steel reaction vessel used for lithium carbide production. Up to 1 percent memory has been found there under extreme conditions in the routine dating system at Harwell. Values of half to one-third this size were more usual, but even etching and scouring the inner surface of the reaction vessel reduced the memory only by a factor of four. This lower limit is believed to exist because of the carburization and decarburization of steel which occurs at the temperature required for the production of lithium carbide. The levels of memory found are of the same order as the levels of significance associated with present radiocarbon techniques. With the accuracy and extended chronologies expected from direct 14G measurement by accelerator techniques, these levels of memory become increasingly important in the preparation of acetylene and pyrolitic graphite (via lithium carbide) used as target materials. This effect, however, can be limited by lowering the temperature of the carbide reaction stage or by lining or impregnating the lithium carbide reaction vessel with some carbon-impermeable alloy or material.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 4
    Publication Date: 1981-01-01
    Description: Routine radiocarbon analyses were last reported for the Laboratory of Isotope Geochemistry at the University of Arizona in 1971 (Haynes, Grey, and Long, 1971), and a special date list on packrat middens appeared in 1978 (Mead, Thompson, and Long, 1978). This list presents results obtained from our gas proportional counting facility before its major renovation and before the addition of a liquid scintillation counting system. The characteristics of these new systems will be described in the next date list.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 5
    Publication Date: 1986-01-01
    Description: In modeling the initial 14C activity of ground waters, the δ13C of marine limestone is taken conventionally to vary little about 0‰ PDB. This variation was found to be 6.28‰ in samples taken over intervals from 10-2 to 105m in the Mooney Falls Member of the Redwall Limestone in northern Arizona. Such a variation will cause appreciable variability in the results of all four initial activity models tested. The variability, due primarily to a numerical instability in the models dependent on this parameter, can introduce significant uncertainty into groundwater “age” calculations.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 6
    Publication Date: 2003-01-01
    Print ISSN: 1527-1404
    Electronic ISSN: 1938-3681
    Topics: Geosciences
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