ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The solvatochromic behaviour of a number of pentacyano-ferrates (II), [FeII(CN)5L] n-, is described, for solutions in H2O-alcohol, -Me2CO and -DMSO mixtures. The strong dependence of solvent sensitivity on the nature of the ligand L is particularly fully documented for H2OMeOH mixtures (0–100% MeOH). The piezochromic behaviour of seven pentacyanoferrates(II) has been established, in aqueous solution. The connection between piezochromism and solvatochromism is detailed, and the solvatochromic results discussed in terms of (preferential) solvation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00191137
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