ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Salt-like compounds [R3NH]⊕[(Cl3Si)2N]⊖ are formed on adding of pyridine, trimethyl or triethylamine to a solution of bis-(trichlorosilyl)amine in petrol ether. The bis(trichlorosilyl)amide ion shows the strongest SiN bonds so far known, with a SiN bond order of 2 and in accordance with the formula [Cl3⊖Si=⊕N=⊖SiCl3].
Notes:
Beim Zutropfen von Pyridin, Trimethyl- oder Triäthylamin in Petroläther zu Bis(trichlorsilyl)amin bilden sich die salzartigen Verbindungen [R3NH]⊕ [(Cl3Si)2N]⊖. Im Bis(trichlorsilyl)amid-ion liegen die bisher stärksten SiN-Bindungen mit einem SiN-Bindungsgrad 2, einer Formel [Cl3⊖Si=⊕N=⊖SiCl3] entsprechend vor.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19723940115
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