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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 17 (1987), S. 361-368 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Poly(vinyl chloride) has been modified chemically to a cation exchange resin by halogen displacement reactions with phenol sulfonic acid, bisphenol-A sulfonic acid and phenolpthalein sulfonic acid. Ion-exchange capacity, salt-splitting capacity and pH-titration characteristics of these resins have been evaluated. pH-titration behaviour of these resins is consistent with that of a polyfunctional cation-exchanger having pK1=2 and pK2=9–10 corresponding to -SO3H and phenolic-OH groups respectively. The ion-exchange capacity values are comparable in magnitude to those of polystyrene based commercial cation-exchangers such as Amberlite IR-120 and Dowex-50.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 18 (1987), S. 472-472 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 1243-1252 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Poly(vinyl chloride) (PVC) has been reacted with dimethylglyoxime (DMG) in THF to form the PVC-DMG comples, which has been characterized by spectroscopic and elemental analyses. The latter indicate that there is one DMG moiety anchored on the PVC chain by displacing every 12th Cl atom in the chain. PVC-DMG has further been reacted with alcoholic solutions of Co(II), Ni(II), and Cu(II) to form the intensely colored PVC-DMG-M(II) complexes. The structures of these complexes have been analyzed by elemental and IR spectral analyses. The overall thermal stability of PVC-DMG-M(II) increases in the order: PVC 〈 PVC-DMG-Cu(II) 〈 PVC-DMG-Ni(II) 〈 PVC-DMG-Co(II). The electrical conductivities are also significantly enhanced in the same order. The permittivities of these complexes are high relative to PVC at low frequency falling gradually with increasing frequency and the dielectric loss-frequency behavior is very broad.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 1703-1710 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: PVC modified by Cl displacement reaction with meta-aminophenol (MAP), bisphenol A (BISA), and phenolphthalein (PHEN) has been converted into phosphoric acid cation exchange resins. These resins have been characterized in regard to their structure, ion exchange properties, and thermal stability. The ion exchange capacities fall into the range 5.5-8.0 (meq/g) for the resins. The overall thermal stability is considerably higher than that for the corresponding sulfonic acid resins, as well as for the PVC-MAP, PVC-BIS A, and PVC-PHEN condensates. The resins exhibit ca. 4-6% capacity losses under isothermal hydrolytic cleavage at 100°C for 24 h.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 1855-1861 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: PVC has been modified by chlorine displacement reaction with m-aminophenol, bisphenol A, and phenophthalein. Sulfonation of these condensates yields bifunctional weak acid resins which do not exhibit —SO3H ionogenic group. Reaction of PVC with presulfonated bisphenol A, phenolphthalein, and phenol yields strong acid resins. Thermal stability characteristics of these various resins have been determined and the results indicate that such modifications improve the overall thermal stability of PVC.
    Additional Material: 4 Ill.
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  • 6
    Publication Date: 1987-11-01
    Print ISSN: 0170-0839
    Electronic ISSN: 1436-2449
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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  • 7
    Publication Date: 1987-04-01
    Print ISSN: 0170-0839
    Electronic ISSN: 1436-2449
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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