ISSN:
1573-9171
Keywords:
structure
;
ansa-complexes
;
titanocenes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The structure of a new ansa compound, (η5-C5H4)CMe2(η5-C9H6)TiCl2 (1), was studied by X-ray analysis:a = 15.00(1),b =15.500(5),c = 13.032(4) Å, β = 92.66°(4),V = 3025.1(1) Å3, space groupP21/α.,R = 0.038. The distorted tetrahedral coordination sphere of the Ti atom is formed by two Cl atoms and two π-ligands. It was proposed that the angle (τ) between theC-M direction and the line normal to M-Cp can be considered as one of the geometric parameters characteristic of the “structure-properties” correlation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00702139
Permalink