Electronic Resource
New York, NY
:
Wiley-Blackwell
Journal für Praktische Chemie/Chemiker-Zeitung
322 (1980), S. 417-422
ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Azoperoxides. VII. Thermolysis of α-AlkylazoalkylhydroperoxidesThe thermal decomposition of 1-methylazo-1-hydroperoxycyclohexane 1 and 1-tert.-butylazo-1-hydroperoxycyclohexane 2 was studied in ethylbenzene and in the case of 2 also in other solvents. Decomposition products and decomposition rates of the azo and the peroxy groups were selectively estimated. The title compounds decompose faster than the analogous azo compounds and alkylhydroperoxides. A induced homolysis of both initiator groups is proposed; the compounds are not „bifunctional initiators“.
Additional Material:
6 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19803220311
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