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  • 1
    Call number: SR 90.0002(497-E)
    In: Professional paper
    Type of Medium: Series available for loan
    Pages: IV, E-46 S. + 5 pl.
    Series Statement: U.S. Geological Survey professional paper 497-E
    Language: English
    Location: Lower compact magazine
    Branch Library: GFZ Library
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 104 (1982), S. 6567-6570 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Algorithmica 23 (1999), S. 261-275 
    ISSN: 1432-0541
    Keywords: Key words. Difference constraints, Incremental algorithm, Linear constraints, Shortest-path problem, Dynamic negative cycle.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract. Difference constraints systems consisting of inequalities of the form x i - x j $ \leq $ b i,j occur in many applications, most notably those involving temporal reasoning. Often, it is necessary to maintain a solution to such a system as constraints are added, modified, and deleted. Existing algorithms handle modifications by solving the resulting system anew each time, which is inefficient. The best known algorithm to determine if a system of difference constraints is feasible (i.e., if it has a solution) and to compute a solution runs in Θ (mn) time, where n is the number of variables and m is the number of constraints. This paper presents a new efficient incremental algorithm for maintaining a solution to a system of difference constraints. As constraints are added, modified, or deleted, the algorithm determines if the new system is feasible and updates its solution. When the system becomes infeasible, the algorithm continues to process changes until it becomes feasible again, at which point a feasible solution will be produced. The algorithm processes the addition of a constraint in time O(m + n log n) and the removal of a constraint in constant time when the original system is feasible. More precisely, additions are processed in time O( || Δ || + |Δ| log|Δ| ) , where |Δ| is the number of variables whose values are changed to compute the new feasible solution, and || Δ || is the number of constraints involving the variables whose values are changed. When the original system is infeasible, the algorithm processes any change in O(m + n log n) amortized time. The new algorithm can also be used to check for the existence of negative cycles in dynamic graphs.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 6613-6631 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: High-resolution near-infrared spectra are reported for all of the O–H stretch vibrational bands of the water dimer. The four O–H vibrations are characterized as essentially independent proton-donor or proton-acceptor motions. In addition to the rotational and vibrational information contained in these spectra, details are obtained concerning the internal tunneling dynamics in both the ground and excited vibrational states. These results show that for tunneling motions which involve the interchange of the proton donor and acceptor molecules, the associated frequencies decrease substantially due to vibrational excitation. The predissociation lifetimes for the various states of the dimer are determined from linewidth measurements. These results clearly show that the predissociation dynamics is strongly dependent on the tunneling states, as well as the Ka quantum number, indicating that the internal tunneling dynamics plays an important role in determining the dissociation rate in this complex.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 1478-1483 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The optothermal molecular beam technique has been used to record the near infrared spectrum of the acetylene–HF binary complex associated with the ν7 vibrational mode (asymmetric C–H stretch). A fit to this perpendicular band spectrum gives accurate rotational constants for both the ground and excited vibrational states, as well as the vibrational origin, namely A‘=1.192 60(5) cm−1 , B‘=0.157 34(1) cm−1 , C‘=0.138 10(1) cm−1 , A'=1.186 90(5) cm−1 , B'=0.157 34(1) cm−1 , C'=0.138 08(1) cm−1, and ν0 =3276.2889(30) cm−1 . From the homogeneous linewidths of the observed transitions the lifetime of the excited vibrational state has been determined to be 3.6 ns. When compared with the lifetime determined previously for the ν1 mode (0.8 ns) and the data obtained previously for several other systems, it is clear that vibrational relaxation in this molecule is mode specific. A discussion is given concerning the nature of this relaxation process.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 5408-5416 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The opto-thermal detection method has been used to obtain rotationally resolved infrared spectra for both (14N14N16O)2 and (15N14N16O)2. The vibrational band observed in each case correlates with the ν1+ν3 band of the N2O monomer. A large number of A- and B-type transitions have been assigned and fit for both species yielding accurate molecular constants for both the ground and excited vibrational states. From intensity alternations associated with nuclear spin statistics and the small inertia defect [Δ‘=0.611 amu A(ring)2 for (14N14N16O)2], it is clear that the nitrous oxide dimer has a slipped parallel geometry which possesses a center of symmetry. Isotopic substitution shows that of the two such structures, only the one having the oxygen atoms close to one another is experimentally observed. The structural constants are determined to be RNN=3.493(4) A(ring) and θNNO=59.2(5)°.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1206-1206 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1262-1267 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Sub-Doppler resolution infrared spectra have been obtained for the ν1 bands of N2 –HCN and OC–HCN using the opto-thermal detection method, from which accurate ground and excited state molecular constants are determined. Vibrational predissociation lifetimes are estimated from the homogeneous broadening of the observed transitions, giving lifetimes of 80 and 2.6 ns for N2 –HCN and OC–HCN, respectively. These lifetimes are considerably longer than those obtained previously for N2 –HF and OC–HF. This difference can be understood in terms of the strength of the coupling between the intra- and intermolecular motions, which is also reflected in the vibrational frequency shift associated with complex formation.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 2196-2204 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Sub-Doppler resolution infrared spectra have been obtained for both the linear and cyclic conformers of the hydrogen cyanide trimer. In the case of the linear trimer, all three vibrational bands correlating with the C–H stretching fundamental of the hydrogen cyanide monomer (ν1) have been observed. The vibrational predissociation lifetime of the complex is found to be strongly mode specific. For the cyclic trimer, which has only one (doubly degenerate) infrared allowed band associated with the C–H stretch, the rotational structure is characteristic of an oblate planar symmetric top. Molecular constants are reported for both conformers. In addition, several other bands are observed in the spectrum which, although not rotationally resolved, are tentatively assigned to the tetramer.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 2185-2195 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Sub-Doppler infrared spectra of two Fermi resonance coupled bands of carbon dioxide dimer have been obtained at 3611.5 and 3713.9 cm−1 using an optothermal molecular beam color-center laser spectrometer. The band origins for the complexes are red shifted by approximately 1 cm−1 from the corresponding ν1+ν3/2ν02+ν3 CO2 bands. The higher frequency band is perturbed while the lower frequency band appears free of extraneous perturbations as determined from a precision fit to a Watson asymmetric rotor Hamiltonian. This fit and the observed nuclear spin statistical weights reveal that the complex is planar with C2h symmetry. The C--C separation and C--C–O angle are determined to be 3.599(7) A(ring) and 58.2(8)°, respectively. The nearest neighbor O--C distance is 3.14 A(ring) which is the same as that found in the crystal. From the centrifugal distortion analysis the weak bond stretching and symmetric bending frequencies are estimated to be 32(2) and 90(1) cm−1. No interconversion tunneling is observed.
    Type of Medium: Electronic Resource
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