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  • 1
    Electronic Resource
    Electronic Resource
    Using faculty publication rates for comparing “peer” institutions (1987)
    Springer
    Research in higher education 27 (1987), S. 163-175 
    Details
    ISSN: 1573-188X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Nature of Science, Research, Systems of Higher Education, Museum Science
    Notes: Abstract This paper reports the results of a study of faculty publication productivity at five major research universities. Data on publication rates were gathered for two years from theCorporate Indexes published by the Institute for Scientific Information, while numbers of faculty by academic discipline were computed using standard reports generated annually by the participating universities. The primary conclusion drawn from the study is that institutional publication rates can be estimated from references in theCorporate Indexes and provide one, albeit imperfect, measure of relative university research productivity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00992367
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    Paper (German National Licenses)
    Fulltext
  • 2
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    Lead Optimization toward Proof-of-Concept Tools for Huntington’s Disease within a 4-(1H-Pyrazol-4-yl)pyrimidine Class of Pan-JNK Inhibitors (2015)
    American Chemical Society (ACS)
    Details
    Publication Date: 2015-03-20
    Description: Journal of Medicinal Chemistry DOI: 10.1021/jm5013598
    Topics: Chemistry and Pharmacology
    Published by American Chemical Society (ACS)
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  • 3
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    Interstellar PAH Emission in the 11-14 micron Region: New Insights and a Tracer of Ionized PAHs (1999)
    In:  Other Sources
    Details
    Publication Date: 2019-07-18
    Description: The Ames infrared spectral database of isolated, neutral and ionized polycyclic aromatic hydrocarbons (PAHs) shows that aromatic CH out-of-plane bending frequencies are significantly shifted upon ionization. For non-adjacent and doubly-adjacent CH groups, the shift is pronounced and consistently toward higher frequencies. The non-adjacent modes are blueshifted by an average of 27 per cm and the doubly-adjacent modes by an average of 17 per cm. For triply- and quadruply-adjacent CH out-of-plane modes the ionization shifts are more erratic and typically more modest. As a result of these ionization shifts, both the non-adjacent and doubly-adjacent CH out-of-plane modes move out of the regions classically associated with their respective vibrations in neutral PAHs. The doubly-adjacent modes of ionized PAHs tend to fall into the frequency range traditionally associated with the non-adjacent modes, while the non-adjacent modes are shifted to frequencies above those normally attributed to out-of-plane bending vibrations. Consequently, the origin of the interstellar infrared emission feature near 11.2 microns, traditionally attributed to the out-of-plane bending of non-adjacent CH groups on PAHs is rendered ambiguous. Instead, this feature likely reflects contributions from both non-adjacent CH units in neutral PAHs and doubly-adjacent CH units in PAH cations, the dominant charge state in the most energetic emission regions. This greatly relieves the structural constraints placed on the interstellar PAH population by the dominance of the 11.2 micron band in this region and eliminates the necessity to invoke extensive dehydrogenation of the emitting species. Furthermore, these results indicate that the emission between 926 and 904 per cm (10.8 and 11.1 microns) observed in many sources can be unambiguously attributed to the non-adjacent CH out-of-plane bending modes of moderately-sized (fewer than 50 carbon atom) PAH cations making this emission an unequivocal tracer of ionized interstellar PAHs.
    Keywords: Astrophysics
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  • 4
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    Obtaining the Mass and Radius of Extra-Solar Giant Planets (1998)
    In:  Other Sources
    Details
    Publication Date: 2019-07-18
    Description: The scientific utility and feasibility of detecting transits of the 9 known extrasolar planets is explored. A transit of a solar-like star by a Jupiter mass planet produces a 1% decrease in the amount of light received from the star. Transit observation will remove the ambiguity in the measurement of the planetary mass inherent in the radial velocity method and confirm the planet's existence. The 9 known planets have a 33% chance of producing at least one observable transit. Additional extrasolar planet detections from the radial velocity surveys will increase this probability to greater than 90%. The radius of the planet can be determined by the fractional decrease in light received during transit. The mass and radius may distinguish rocky or gas giant planets from brown dwarfs. The probability of detection, the transit signal size and duration, and predictions of the transit times (including errors) are calculated for circular and elliptical orbits. Observational limits are investigated and it is shown that small telescopes and existing detectors are adequate enough to achieve the 0.1% photometry necessary to detect transits of the known extrasolar planets.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Protostars and Planets Conference; Jul 06, 1998 - Jul 11, 1998; United States
    Format: text
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  • 5
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    Power Management in Regenerative Life Support Systems (1999)
    In:  Other Sources
    Details
    Publication Date: 2019-07-17
    Description: Effective management of power can reduce the cost of launch and operation of regenerative life support systems. Variations in power may be quite severe and may manifest as surges or spikes, While the power plant may have some ability to deal with these variations, with batteries for example, over-capacity is expensive and does nothing to address the fundamental issue of excessive demand. Because the power unit must be sized to accommodate the largest demand, avoiding power spikes has the potential to reduce the required size of the power plant while at the same time increasing the dependability of the system. Scheduling of processors can help to reduce potential power spikes. However, not all power-consuming equipment is easily scheduled. Therefore, active power management is needed to further decrease the risk of surges or spikes. We investigate the use of a hierarchical scheme to actively manage power for a model of a regenerative life support system. Local level controllers individually determine subsystem power usage. A higher level controller monitors overall system power and detects surges or spikes. When a surge condition is detected, the higher level controller conducts an 'auction' and describes subsystem power usage to re-allocate power. The result is an overall reduction in total power during a power surge. The auction involves each subsystem making a 'bid' to buy or sell power based on local needs. However, this re-allocation cannot come at the expense of life support function. To this end, participation in the auction is restricted to those processes meeting certain tolerance constraints. These tolerances represent acceptable limits within which system processes can be operated. We present a simulation model and discuss some of our results.
    Keywords: Man/System Technology and Life Support
    Type: International Conference on Environmental Systems; Jul 10, 2000 - Jul 13, 2000; Toulouse; France
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  • 6
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    Prebiotic Nitrogen Fixation by FeS Reduction of Nitrite Under Acidic Conditions (1999)
    In:  Other Sources
    Details
    Publication Date: 2019-07-18
    Description: Theories for the origin of life require the availability of reduced nitrogen for the formation of such species as amino acid and nucleic acids. In a strongly reducing atmosphere, compounds essential to the chemical evolution of life, such as amino acids, can form by reactions between HCN, NH3, and carbonyl compounds produced in spark discharges. However, under non-reducing atmospheres, electric discharges produced NO rather than HCN or NH3. This raises the questions of; how ammonia can be formed under a neutral atmosphere, and what conditions are needed such formation to occur? On possibility is the conversion of NO into nitric and nitrous acids (through HNO) and rained into the oceans. The reduction of nitrite by aqueous Fe(II) (6 Fe(+2) + 7 H(+) + NO2(-) yields 6 Fe(III) + 2 H2O + NH3) such as was present on the early Earth could then have produced ammonia. However, this reaction does not proceed at pHs less than 7.3. An alternative is reduction by other forms of Fe(II), such as FeS. We will present results that show that FeS can reduce nitrite to ammonia at pHs as low as pH 5 under a variety of conditions.
    Keywords: Life Sciences (General)
    Type: 9th ISSOL Meeting; Jul 11, 1999 - Jul 16, 1999; San Diego, CA; United States
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  • 7
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    Variations in the Strength of the Infrared Forbidden 2328.2 cm-1 Fundamental of Solid N2 in Binary Mixtures (2002)
    In:  CASI
    Details
    Publication Date: 2019-07-10
    Description: We present the 2335-2325 cm(exp -1) infrared spectra and band positions, profiles, and strengths (A values) of solid nitrogen and binary mixtures of N2 with other molecules at 12 K. The data demonstrate that the strength of the infrared forbidden N2 fundamental near 2328 cm(exp -1) is moderately enhanced in the presence of NH3, strongly enhanced in the presence of H2O and very strongly enhanced in the presence of CO2, but is not significantly affected by CO, CH4, or O2. The mechanisms for the enhancements in N2-NH3 and N2-H2O mixtures are fundamentally different from those proposed for N2-CO2 mixtures. In the first case, interactions involving hydrogen-bonding are likely the cause. In the latter, a resonant exchange between the N2 stretching fundamental and the O-18=C-12 asymmetric stretch of O-18C-12O-16 is indicated. The implications of these results for several astrophysical issues are briefly discussed.
    Keywords: Inorganic, Organic and Physical Chemistry
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  • 8
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    The Spacing of the Interstellar 6.2 Microns and 7.7 Microns Emission Features as an Indicator of PAH Size (1998)
    In:  Other Sources
    Details
    Publication Date: 2019-07-10
    Description: A database of astrophysically relevant, infrared spectral measurements on a wide variety of neutral as well as positively and negatively charged polycyclic aromatic hydrocarbons ranging in size from C10H8 through C48H20 is now available to extend the interstellar PAH model. Beyond simply indicating general characteristics of the carriers, this collection of data now makes it possible to conduct a more thorough interpretation of the details of the interstellar spectra and thereby derive deeper insights into the nature of the emitting material and conditions in the emission zones. This paper is the first such implementation of this spectral database. The infrared spectra of PAH cations, the main PAH form in the most energetic emission zones, are usually dominated by a few strong features in the 1650 - 1100 per centimeter (6.1 - 9.1 microns) region which tend to cluster in the vicinity of the interstellar emission bands at 1610 per centimeter and 1320 per centimeter (6.2 and 7.6 microns) but with spacings typically somewhat less than that observed in the canonical interstellar spectrum. However, the spectra in the database show that this spacing increases steadily with molecular size. Extrapolation of this trend indicates that PAHS in the 50 to 80 carbon atom size range are entirely consistent with the observed interstellar spacing. Furthermore, the profile of the 1610 per centimeter (6.2 microns) interstellar band indicates that PAHS containing as few as 20 carbon atoms contribute to this feature.
    Keywords: Astrophysics
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  • 9
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    The Production of Polycyclic Aromatic Hydrocarbon Anions in Inert Gas Matrices Doped with Alkali Metals. Electronic Absorption Spectra of the Pentacene Anion (C22H14(-)) (1999)
    In:  CASI
    Details
    Publication Date: 2019-07-10
    Description: The absorption spectra of pentacene (C22H14) and its radical cation (C22H14(+)) and anion (C22H14(-)) isolated in inert-gas matrices of Ne, Ar, and Kr are reported from the ultraviolet to the near-infrared. The associated vibronic band systems and their spectroscopic assignments are discussed together with the physical and chemical conditions governing ion (and counterion) production in the solid matrix. In particular, the formation of isolated pentacene anions is found to be optimized in matrices doped with alkali metal (Na and K).
    Keywords: Inorganic, Organic and Physical Chemistry
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  • 10
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    EEG Analysis of the Effects of Therapeutic Cooling on the Cognitive Performance of Multiple Sclerosis Patients (1999)
    In:  CASI
    Details
    Publication Date: 2019-07-10
    Description: The objective of this project was to determine whether a controlled period of head and torso cooling would enhance the cognitive performance of multiple sclerosis patients. Nineteen MS patients (11 men and 8 women) participated in the study. Control data were taken from nineteen healthy volunteers (12 men and 7 women). All but six of nineteen MS patients tested improved their cognitive performance, as measured by their scores on the Rao test battery. A second objective was to gain insight into the neurological effects of cooling. Visual evoked potentials (VEPs) stimulated by a reversing checkerboard pattern were recorded before and after cooling. We found that cooling selectively benefited the cognitive performance of those MS patients whose pre-cooling VEPs were abnormally shaped (which is an indication of visual pathway impairment due to demyelinization). Moreover, for female MS patients, the degree of cognitive performance improvement following cooling was correlated with a change in the shape of their VEPs toward a more normal shape following cooling.
    Keywords: Aerospace Medicine
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