ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Compounds C6H5X(X = F, Cl, Br, NO2, CN, OCH3) have been studied under chemical ionization conditions with ammonia as reagent gas. A pulsed electron beam and time resolved ion collection has allowed the determination of the reaction leading to the formation of [C6H5NH3]+ (m/z 94). [NH4]+ reacts with C6H5X(X = F, Cl, Br) to yield m/z 94 but C6H5X (X = CN, NO2) forms this ion only by reactions involving either [NH3]+ or [C6H5X]+. C6H5OCH3 does not form m/z 94.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210190805
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