ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The one photon (optical), and two and three photon resonant multiphoton spectra of trans-hexatriene have been recorded and analyzed. Transitions to the 3s, 3px(Ag), 3py¯(Bg), 3dy¯z¯(Au), and 4s(3d) orbitals (states) have been observed. Vibrational modes ag: C=C stretch, CH2 rock, and CH and CCC deformations, au: CH and skeletal torsions, bu: C=C stretch have been observed in many of the studied Rydberg states. The assignments of the electronic states and vibrational modes are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.448956
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