ISSN:
1600-5775
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Geosciences
,
Physics
Notes:
Dehydration process in recently synthesized porous inorganic salts formed by large cluster anions [Re6X8(CN)6]4- (X= S, Se), transition metal cations and water molecules has been investigated. Desolvation process of the complex Co(DMF)6[Mo6Br8(NCS)6], where DMF - dimethylformamide, has been studied. CoK, MoK and ReL3 XAFS measurements of these new complicated compounds before and after annealing in vacuum at temperature up to 250°C were performed. Changes of electronic and spatial structure of these compounds under the heating process have been established and adequate structural models of the amorphous compounds obtained are suggested and discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0909049501000176
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