ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Resonance enhanced Raman spectra are reported for the complexes M(bpy-d8)32+[M=Fe(II), Ru(II)] and Ru(bpy-d8)2Cl2, where bpy-d8 is perdeuteriated 2,2′-bipyridine. Correlations are made with the corresponding resonance enhanced modes of the hydrogen containing compounds for the spectra obtained in resonance with the visible metal to ligand charge-transfer (MLCT) absorption bands. In particular, the effect of in-plane C—H(D) deformation modes on the resonance active vibrations is discussed.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250150208
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