ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On a [3 + 1] Cycloaddition, II. Reactions of 4,5-Dihydro-1,3,5-oxazaphosph(V)olen, VI4,5-Dihydro-1,3,5-oxazaphosph(V)oles 1 react with isonitriles to yield disubstituted 3-imino-4,4-bis(trifluoromethyl)-1-azetines 2 with elimination of phosphoric acid esters. The reaction should proceed via nitrile ylides.
Notes:
4,5-Dihydro-1,3,5-oxazaphosph(V)ole 1 reagieren mit Isonitrilen zu disubstituierten 3-Imino-4,4-bis(trifluormethyl)-1-azetinen 2 unter Ehmmierung von Phosphorsäureester Eine Nitrilylid-Zwischenstufe wird angenommen.
Additional Material:
6 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19731060102
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