ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(Hexamethylphosphoric triamide)lithium Dicyanomethanide, [LiCH(CH)2]n a Polymer Containing the Malonodinitrile AnionThe preparation and crystal structure of the title compound [LiCH(CN)2(hmpt)]n [HMPT = O=P(NMe2)3] are described. The polymeric compound contains structural units of … LiNCC(H)CNLi…as double chains. They are linked by planar Li2O2 rings involving the HMPT ligands. The experimental structure parameters of the dicyanomethanide (malonodinitrile) anion correspond well with previous MO calculations. Results of 1H- and 13C-NMR investigations are also reported.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19881210628
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