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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Environmental science & technology 27 (1993), S. 1611-1615 
    ISSN: 1520-5851
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 65 (1993), S. 287-292 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 580-582 (June 2008), p. 401-404 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An in-house developed FE code, based on the idea of Iterative Substructure Method, wasused to evaluate the effectiveness of fixture and pre-strain for reduction of welding distortion in afillet welded structure. Comparison between the simulation results and experimental results hasbeen performed to validate the basic FE model. Effects of two fixture conditions and various prestrainschemes were analyzed. The simulation results show that appropriate fixture can greatlyreduce angular distortion of the work-piece and results in an appreciable reduction in residualdeformation and the application of pre-strain can significantly reduce the residual distortion
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 30 (1989), S. 668-672 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: The quantum inverse scattering method is used for the study of a nonlinear N-wave resonance interaction system. The Yang–Baxter relations are solved to get various commutation relations for the scattering data operators. The energy spectrum of the quantum Hamiltonian for the model is determined and the existence of the quantum bound states is analyzed. In the classical limit, the corresponding r matrix is found, and the well-established correspondence between the classical solitons and the quantum bound states is examined. Finally, the integrability of the same model but with both fermion fields and boson fields is discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters A 143 (1990), S. 288-292 
    ISSN: 0375-9601
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 8062-8071 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The microwave spectra of seven isotopic species of methyl cyanoformate, CD3OC(O)CN, CD2HOC(O)CN, 13CH3OC(O)CN, CH318OC(O)CN, CH3O13C(O)CN, CH3OC(O)13CN and CH3OC(O)C15N have been measured and assigned. A barrier to internal rotation of 407±1 cm−1 (1164±3 cal/mol) has been obtained for seven symmetric internal rotor species from the internal rotation analyses. The rotational constants from nine isotopic species have been used to determine both rs and r0 structural parameters for the s-trans conformer (methyl group trans to the cyanide group). All independent structural parameters could be determined. Optimized structures were calculated for the s-trans conformer by ab initio Hartree–Fock gradient calculations with both the 3-21G and 6-31G* basis sets as well as with MP2/6-31G* calculations. With the 6-31G* basis set, the barrier to interconversion of the s-trans form to the s-cis form was calculated to be 4055 cm−1 (11.59 kcal/mol) with the s-trans conformer being more stable by 2364 cm−1 (6.76 kcal/mol). The barrier to internal rotation of the methyl group was calculated to be 442 cm−1 (1264 cal/mol).
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 67 (1996), S. 3252-3259 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A bond graph model of the sample extraction/injection system of a prototype portable gas chromatographic instrument has been developed. In addition to performing the same functions as current portable gas chromatographs (GCs), the new generation of GC instruments is designed to perform extraction of analytes from liquid and solid samples. The prototype instrument achieves these improvements by taking of advantage of microfabrication technologies and microprocessor control in the design. A novel sample extraction/injection module is essential to the improved performance of the portable instrument, which will include microfabricated components such as inlets, interface chips, fluid channels, control valves, optimal heater/sensor combinations, and multiport connectors. In order to achieve the desired analytical performance, all of the major components are heated to 250 °C during different stages of a sample analysis. Predicting the performance of the system in this operating regime requires the modeling and analysis of system behavior in two interacting energy domains, fluid and thermal. This article represents the first effort to understand the dynamic behavior of the thermofluid aspect of micro-GC instruments and one of the first attempts to apply the widely-used bond graph technique to modeling and analysis of microsized thermofluid systems. Simulation results using the bond graph model closely match available experimental data, with differences typically less than 10%. This demonstrates that fluid dynamic theory for macroscale systems, and the bond graph method based on it, can be readily applied to microscale systems with these dimensions. The bond graph method can be a useful computer-aided design tool for the development of a new generation of truly integrated micro-GC instruments and sensors fabricated with micromachining technology. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 31 (1990), S. 1544-1550 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: Hidden local gauge invariance in the one-dimensional (1-D) Hubbard model and its equivalent coupled spin model is studied. It is found that Abelian U(1)⊗U(1) gauge transformations appear in both cases. Furthermore, it is shown that the energy spectrum is gauge invariant whereas the eigenvectors are explicitly gauge dependent. However, this result relies heavily on Shastry's conjecture about the eigenvalue of the transfer matrix for the 1-D Hubbard model. Lastly, there is also a discrete symmetry associated to Z2⊗Z2. Once this symmetry is broken, one immediately obtains another nontrivial solution to the Yang–Baxter relations. UFaipxr
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 18 (2000), S. 85-90 
    ISSN: 1573-4846
    Keywords: sol-gel ; silica sorbent ; metal removal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Chemically doped sol-gel silica has been developed by entrapping organic dye cibacron blue as a complexing reagent in porous silica prepared by the sol-gel method for removal of metal ions from water samples. In the doped sol-gel silica, the large reagent molecules are entrapped inside the pores while small metal ions can diffuse into the pores where they are complexed by the reagent and retained inside the pores. This new solid sorbent was tested for removal of Zn(II) from aqueous solutions. The kinetics, isotherm, and pH effect of the removal were investigated. With a loading of 0.10 mmol cibacron blue/g, the sol-gel silica sorbent had a capacity of 0.09 mmol Zn/g. It was demonstrated that the sol-gel silica sorbent could be regenerated and reused repeatedly.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Stochastic environmental research and risk assessment 12 (1998), S. 117-140 
    ISSN: 1436-3259
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Transport of non-ergodic solute plumes by steady-state groundwater flow with a uniform mean velocity, μ, were simulated with Monte Carlo approach in a two-dimensional heterogeneous and statistically isotropic aquifer whose transmissivity, T, is log-normally distributed with an exponential covariance. The ensemble averages of the second spatial moments of the plume about its center of mass, 〈S i i (t)〉, and the plume centroid covariance, R i i (t) (i=1,2), were simulated for the variance of Y=log T, σ Y 2=0.1, 0.5 and 1.0 and line sources normal or parallel to μ of three dimensionless lengths, 1, 5, and 10. For σ Y 2=0.1, all simulated 〈S i i (t)〉−S i i (0) and R i i (t) agree well with the first-order theoretical values, where S i i (0) are the initial values of S i i (t). For σ Y 2=0.5 and 1.0 and the line sources normal to μ, the simulated longitudinal moments, 〈S 11(t)〉−S 11(0) and R 11(t), agree well with the first-order theoretical results but the simulated transverse moments 〈S 22(t)〉−S 22(0) and R 22(t) are significantly larger than the first-order values. For the same two larger values of σ Y 2 but the line sources parallel to μ, the simulated 〈S 11(t)〉−S 11(0) are larger than but the simulated R 11 are smaller than the first-order values, and both simulated 〈S 22(t)〉−S 22(0) and R 22(t) stay larger than the first-order values. For a fixed value of σ Y 2, the summations of 〈S i i (t)〉−S i i (0) and R i i , i.e., X i i (i=1,2), remain almost the same no matter what kind of source simulated. The simulated X 11 are in good agreement with the first-order theory but the simulated X 22 are significantly larger than the first-order values. The simulated X 22, however, are in excellent agreement with a previous modeling result and both of them are very close to the values derived using Corrsin's conjecture. It is found that the transverse moments may be significantly underestimated if less accurate hydraulic head solutions are used and that the decreasing of 〈S 22(t)〉−S 22(0) with time or a negative effective dispersivity, defined as , may happen in the case of a line source parallel to μ where σ Y 2 is small.
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