ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The reduction of H+ cations on the Pt electrode coated with poly(N-methylpyrrole) (PNMP) film was studied in an acidic aqueous solution. The reduction depends strongly on the counteranions originally doped in PNMP during polymerization. H+ cations can penetrate the neutral or overoxidized film from PNMP(TsO-), in which the H+ diffusion coefficient is estimated as 10-5 cm2 s-1 by the potential step chronoamperometry method. But the neutral or overoxidized film from PNMP(NO3-) is closed for H+ penetration. © 1996 John Wiley & Sons, Inc.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
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