Publication Date:
2017-06-13
Description:
The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+cation and two NO3−anions. In the complex, [Co(C20H14N4S)(H2O)2]2+cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoIIcation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2coordination sphere. The NO3−anions are linked to the [Co(C20H14N4S)(H2O)2]2+cationsviaO—H...O hydrogen bonds, yielding a layered arrangement parallel to (001).
Electronic ISSN:
2056-9890
Topics:
Chemistry and Pharmacology
,
Geosciences
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