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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Section 27 (1971), S. 1703-1712 
    ISSN: 0584-8539
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Crystal Growth 47 (1979), S. 121-123 
    ISSN: 0022-0248
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Crystal Growth 51 (1981), S. 373-376 
    ISSN: 0022-0248
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 54 (1998), S. 1104-1105 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 55 (1999), S. 1247-1248 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1434-4475
    Keywords: Keywords. Acetylacetone; Benzoylacetone; Dibenzoylmethane; Thienoyltrifluoroacetone; Dissociation constant; Single crystals.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung.  Schiffsche Basen von Acetylaceton, Benzoylaceton, Dibenzoylmethan und Thienoyltrifluoroaceton mit Ethanolamin und 2-Aminophenol wurden hergestellt und mittels Elementaranalyse, IR-Spektroskopie und 1H-NMR-Spektroskopie charakterisiert. Die Dissoziationskonstanten wurden in Ethanol-Wasser bei einer lonenstärke von 0.1 M KNO3 bei verschiedenen Temperaturen bestimmt; die entsprechenden thermodynamischen Größen wurden berechnet. Das Röntgendiffraktionsmuster eines Einkristalls einer der Verbindungen wurde analysiert. Thermische Untersuchungen wurden durchgeführt und die Ergebnisse mit den Strukturen korreliert.
    Notes: Summary.  Schiff bases of acetylacetone, benzoylacetone, dibenzoylmethane, and thienoyltrifluoroacetone with ethanolamine and 2-aminophenol were synthesized and characterized by elemental analysis, infrared and 1H NMR spectra. Dissociation constants of the synthesized ligands were determined in methanol-water and at an ionic strength of 0.1 M KNO3 at different temperatures; the associated thermodynamic parameters were calculated. Single crystals of one of the ligands were prepared; the X-ray diffraction pattern was analyzed. Thermal analyses of the investigated ligands were performed and correlated with the ligand structure.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 408 (1974), S. 255-260 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: IR Spectra and Forcefields of Ternary Alkali-Yttrium Fluorides with Elpasolite StructureIR spectra of A2BYF6 are reported and five force constants are calculated using a modified valence force field. The results are discussed with respect to the two bond characters.
    Notes: Es werden die IR-Spektren von A2BYF6 (A = K, Rb, Cs; B = Na, K, Rb, Cs) mitgeteilt und daraus mittels eines modifizierten Valenzkraftfeldes fünf Kraftkonstanten berechnet. Die Ergebnisse werden für die beiden Bindungsarten diskutiert.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 420 (1976), S. 210-218 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Vibrational Spectra and Force Constants of the Elpasolites Cs2KMF6 (M = Sc, Y, La, Gd, Yb)The vibrational spectra of the elpasolites Cs2KMF6 (M = Sc, Y, La, Gd, Yb) have been recorded and assigned including the lattice vibrations. The vibrational frequencies thus obtained were used for the calculation of XVFF force constants. The values of the stretching force constants are discussed.
    Notes: Die Schwingungsspektren der Elpasolithe Cs2KMF6 (M = Sc, Y, La, Gd, Yb) wurden aufgenommen und einschließlich der Gitterschwingungen zugeordnet. Die so erhaltenen Frequenzwerte wurden zur Berechnung von Kraftkonstanten nach einem modifizierten Valenzkraftfeld benutzt. Der Gang der Valenzkraftkonstanten wird diskutiert.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 1750-1754 
    ISSN: 0044-2313
    Keywords: Cobalt Complexes ; Pyrazine ; Gel Crystallization ; Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Growth and Structure of CoSO4 · Pyrazine · 6 H2O (I) and (CoSO4)2 · Pyrazine · 12 H2O (II)Single crystals of μ-pyrazino-bis[pentaquacobalt(II)]-sulfate-dihydrate CoSO4(pz) · 6 H2O and Tetraqua-μ-pyrazino-cobalt(II)sulfate-dihydrate (CoSO4)2(pz) · 12 H2O were grown by using gel methods and investigated by X-ray analysis. CoSO4(pz) · 6 H2O (I) shows monoclinic symmetry, space group C2/c; a = 1006.4(4) pm, b = 1026.9(4) pm, c = 1261.5(2) pm; β = 104.01(4)°; Z = 4. (CoSO4)2(pz) · 12 H2O (II) shows orthorhombic symmetry, space group Pbam; a = 1262.3(4) pm, b = 1231.3(4) pm, c = 684.1(2) pm; Z = 2. CoSO4 and Pyrazine crystallize in a polymeric (I) as well as in a dimeric (II) compound. In the polymeric compound the molecules are bonded by pyrazine to form alternating linear chains. The dimer is a dinuclear complex with a bridging pyrazine molecule.
    Notes: μ-Pyrazino-bis[pentaquacobalt(II)]sulfatdihydrat (CoSO4 · Pyrazin · 6 H2O) und Tetraqua-μ-pyrazino-cobalt(II)sulfat-dihydrat ((CoSO4)2 · Pyrazin · 12 H2O) wurden mittels der Gelmethode synthetisiert und röntgenographisch untersucht. CoSO4 · Pz · 6 H2O (I) kristallisiert monoklin, Raumgruppe C2/c, a = 1006,4(4) pm, b = 1026,9(4) pm, c = 1261,5(2) pm; β = 104,01(4)°; Z = 4. (CoSO4)2 · Pz · 12 H2O (II) kristallisiert orthorhombisch, Raumgruppe Pbam, a = 1262,3(4) pm, b = 1231,3(4) pm, c = 684,1(2) pm; Z = 2. Zwischen CoSO4 und Pyrazin läßt sich neben einer polymeren (I) auch eine dimere Verbindung (II) kristallisieren. Der polymeren Verbindung liegen lineare, in ihrer Richtung alternierende Ketten zugrunde. Das Dimere liegt als pyrazinverbrückter Zweikernkomplex vor.
    Additional Material: 3 Ill.
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  • 10
    ISSN: 1862-0760
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Some oxides with the scheelite structure are well known mixed ionic and electronic conductors. This structure family, with the general composition ABO4, can be described as a layer structure derivative of the fluorite structure. The relations between the structural and the electrical transport properties of these materials have been investigated. The model system used in this work was BiVO4, which shows both electronic and ionic conduction. Single crystals of bismuth vanadate (BiVO4) were grown using the Czochralski technique. Single crystal boules up to 55 mm in diameter and up to 30 mm long were produced. The crystallographic orientation was determined by the Laue method, and they were cleaved along [001] planes and polished to optically perfect cubes with an edge length of 5 mm. Two-point ac impedance measurements in the temperature range between 550°C and 700°C were performed. The conductivities were measured as a function of the crystal orientation and showed strong anisotropy as expected from the crystal structure.
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