ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The Schiff base N-(tert-butyl)-3-methoxysalicylaldimine (LH) forms a complex with gadolinium(III) chloride, [GdCl2(LH)2(C5H5N)2]+, in which the two O atoms of each ligand are coordinated (the phenolic O atom being deprotonated) and the imine N atom is protonated and involved in a hydrogen bond with the phenoxide group. This complex crystallizes as an ion pair with uranyl tetrachloride, i.e. bis{bis[2-(tert-butyliminiomethyl)-6-methoxyphenolato-O,O′]dichlorobis(pyridine-N)gadolinium(III)} tetrachlorodioxouranium(VI) tetrapyridine solvate [GdCl2(C12H17NO2)2(C5H5N)2]2[UCl4O2]·4C5H5N. The U atom of the UCl4O2 anion lies on an inversion centre.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101001445
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