ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
This paper emphasizes the complementarity between optical and magneto-optical measurements on f elements. The magnetic circular dichroism, circular dichroism, and polarized absorption spectra of Na3Nd(ODA)3⋅2NaClO4⋅6H2O (NdODA), have been recorded at 4.2 K between 5000 and 30 000 cm−1. The electric dipole contributions to the f–f transitions are analyzed using a parametric model which contains 12 parameters which are determined by fitting the calculated to the empirical dipole strengths of 50 α and 16 π polarized absorption lines. The reliability of these intensity parameters is tested by simulating the more sensitive magneto-optical (magnetic circular dichroism) and chiroptical (circular dichroism) spectra. © 1996 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.472471
Permalink