ALBERT

Description: A decade of particle flux measurements providse the basis for a comparison of the eastern and western province s of the Nordic Seas. Ice-related physical and biological seasonality as well as pelagic settings jointly control fluxes in the western Polar Province which receive s southward flowing water of Polar origin. Sediment trap data from this realm highlight a predominantly physical flux control which leads to exports of siliceous particle s within the biological marginal ice zone as a prominent contributor. In the northward flowing waters of the eastern Atlanti c Province, feeding strategies, life histories and the succession ofdominant mesozooplankters (copepods and pteropods) are central in controlling fluxes. Furthermore, more calcareous matter is exported here with a shift in flux seasonality towards summer I autumn. Dominant pelagic processes modeled numerically as to their impact on annual organic carbon exports for both provinces confirm that interannual flux variability is related to changes in the respecti ve control mechanisms. Annual organic carbon export s are strikingly similar in the Polar and Atlantic Province s (2.4 and 2.9 g/m**2/y at 500 m depth), despite major differences in flux control. The Polar and Atlantic Provinces, however, can be distinguished according to annual fluxes of opal (1.4 and 0.6 g/m**2/y) and carbonate (6.8 and 10.4 g/m**2/y). Interannual variability may blur this in single years. Thus, it is vital to use multi-annual data sets when including particle exports in general biogeochemical province descriptions. Vertical flux profiles (collections from 500 m, 1000 m in both provinces and 300-600 m above the seafloor deviate from the general vertical decline of fluxes due to particle degradation during sinking. At depths〉 1000 m secondary fluxes (laterally advectedlresuspended particles) are often juxtaposed to primary (pelagic) fluxes, a pattern which is most prominent in the Atlantic Province. Spatial variability within the Atlantic Province remains poorly understood, and the same holds true for interannual variability. No proxies are at hand for this province to quantitatively relate fluxes to physical or biological pelagic properties. For the seasonally ice-covered Polar Province a robust relationship exists between particle export and ambient ice-regime (Ramseier et al. this volume; Ramseier et al. 1999). Spatial flux patterns may be differentiated and interannual variability can be analyzed in this manner to impro ve our ability to couple pelagic export patterns with benthic and geochemical sedimentary processes in seasonally ice-covered seas.

Description: A decade of particle flux measurements providse the basis for a comparison of the eastem and westem provinces ofthe Nordic Seas. Ice-related physical and biological seasonality as well as pelagic settings jointly control fluxes in the westem Polar Province which receives southward flowing water of Polar origin. Sediment trap data from this realm highlight a predominantly physical flux control which leads to exports of siliceous particles within the biological marginal ice zone as a prominent contributor. In the northward flowing waters of the eastem Atlantic Province, feeding Strategie . life histories and the succession of dominant mesozooplankters (copepods and pteropods) are central in controlling fluxes. Furthermore, more calcareous matter is exported here with a shift in flux seasonality towards surnrner/autumn. Dominant pelagic processes modeled numerically as to their impact on annual organic carbon exports for both provinces confirrn that interannual flux variability is related to changes in the respective control mechanisms. Annual organic carbon exports are strikingly similar in the Polar and Atlantic Provinces (2.4 and 2.9 g m-2 y-1 at 500 m depth). despite major differences in flux control. The Polar and Atlantic Provinces. however, can be distinguished according to annual fluxes of opal ( l.4 and 0.6 g m-2 y-1) and carbonate (6.8 and 10.4 g m-2 y-1). lnterannual variability may blur this in single years. Thus. it is vital to use multi-annual data sets when including particle exports in general biogeochemical province descriptions. Vertical flux profiles (collections from 500 m, l000 min both provinces and 300-600 m above the seafloor deviate from the general vertical decline of fluxes due to particle degradation during sinking. At depths 〉 1000 m secondary fluxes (laterally advected/re uspended particles) are often juxtaposed to primary (pelagic) fluxes, a pattem which is most prominent in the Atlantic Province. Spatial variability within theAtlantic Province remains poorly understood. and the same holds true for interannual variability. No proxies are at hand for this province to quantitatively relate fluxes to physical or biological pelagic properties. For the easonally ice-covered Polar Province a robust relationship exists between particle export and ambient ice-regime (Ramseier et al. this volume; Ramseier et al. 1999). Spatial flux pattems may be differentiated and interannual variability can be analyzed in this manner to improve our ability to couple pelagic export pattems with benthic and geochemical sedimentary processes in seasonally ice-covered seas.

Description: A new underway system combining infrared detection and the OA-ICOS technique was coupled to a continuos equilibrator in order to perform highly-resolved measurements of atmospheric and oceanic N2O and CO2 in the equatorial Atlantic Ocean during the SOPRAN cruises MSM 18, legs 2 and 3 (May-July 2011). Seawater measurements agreed with discrete samples and the slight differences are mostly due to uncertainty in the sample collection while steep gradients were crossed. During MSM 18/2 high values of oceanic fCO2 and pN2O with respect to the overlying atmosphere led to positive sea-air differences as large as 70 µatm CO2 and 159 natm N2O. Analysis of similar cross-equatorial sections at different times revealed that the strength of this source increased in association with the onset of equatorial upwelling on early June, when the lowest SST coincide with the highest (positive) ΔfCO2 and ΔpN2O close to 10°W.

Description: A new system for continuous, highly-resolved oceanic and atmospheric measurements of N2O, CO and CO2 is described. The system is based upon off-axis integrated cavity output spectroscopy (OA-ICOS) and a non-dispersive infrared analyzer (NDIR) both coupled to a Weiss-type equilibrator. Performance of the combined setup was evaluated by testing its precision, accuracy, long-term stability, linearity and response time. Furthermore, the setup was tested during two oceanographic campaigns in the equatorial Atlantic Ocean in order to explore its potential for autonomous deployment onboard voluntary observing ships (VOS). Improved equilibrator response times for N2O (2.5 min) and CO (45 min) were achieved in comparison to response times from similar chamber designs used by previous studies. High stability of the OA-ICOS analyzer was demonstrated by low optimal integration times of 2 and 4 min for N2O and CO respectively, as well as detection limits of 〈 40 ppt and precision better than 0.3 ppb Hz−1/2. Results from a direct comparison of the method presented here and well-established discrete methods for oceanic N2O and CO2 measurements showed very good consistency. The favorable agreement between underway atmospheric N2O, CO and CO2 measurements and monthly means at Ascension Island (7.96°S 14.4°W) further suggests a reliable operation of the underway setup in the field. The potential of the system as an improved platform for measurements of trace gases was explored by using continuous N2O and CO2 data to characterize the development of the seasonal equatorial upwelling in the Atlantic Ocean during two RV/ Maria S. Merian cruises. A similar record of high-resolution CO measurements was simultaneously obtained offering for the first time the possibility of a comprehensive view on the distribution and emissions of these climate relevant gases on the area. The relatively simple underway N2O/CO/CO2 setup is suitable for long-term deployment on board of research and commercial vessels although potential sources of drift such as cavity temperature and further technical improvements towards automation still need to be addressed.