ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The oxide of the macrocyclic phosphine and its acyclic analog have been synthesized, as well as complexing agents of the monopodand type. 2. By using model compounds it has been shown that when the phosphoryl-containing macrocycle complexes with the lithium ion, the phosphoryl group oxygen and, apparently, the central ethereal oxygen, participate in the coordination. For ions of greater radius, the ether oxygens only are involved. 3. In the phosphoryl-containing podands, coordination with the lithium ion via the phosphoryl groups is preferred. In complex formation with ions of larger radii, the ether oxygens participate in the coordination.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00953332
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