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  • 1
    Electronic Resource
    Electronic Resource
    Kinetics and mechanism of α-olefin isomerization in the presence of Co(N2)(PPh3)3 (1977)
    Springer
    Reaction kinetics and catalysis letters 7 (1977), S. 247-251 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Обнаружено промотирующее влияние азота на активность комплекса Co(N2)(PPh3)3 в реакции изомеризации α-олефинов. Установлено, что каталитически активными являются комплексы Co(L)(PPh3)3, где L−N2 или олефин. Изучена кинетика изомеризации гексена-1, распределение дейтерия при изомеризации 1-пентена-1,2 D2 и предложен кинетический механизм процесса.
    Notes: Abstract Nitrogen was found to promote the isomerization of α-olefins in the presence of Co(N2)(PPh3)3. Complexes of the type Co(L)(PPh3)3. where L is N2 or olefin, are catalytically active. The kinetics of 1-hexene isomerization and the deuterium distribution in 1-pentene-d1, d2 have been studied and a mechanism is proposed for this process.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02062451
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  • 2
    Electronic Resource
    Electronic Resource
    Interaction of styrene with triphenylphosphinecobalt complexes (1978)
    Springer
    Reaction kinetics and catalysis letters 9 (1978), S. 113-117 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract В продуктах взаимодействия фосфиновых комплексов кобальта Co(N2)(PPh3)3, HCo(N2)(PPh3)3 и H3Co(PPh3)3 со стиролом методом ЭПР идентифицированы монои биядерные комплексы кобальта. Установлено, что при каталитическом гидрировании стирола одним из промежуточных соединений является парамагнитный комплекс Co(PPh3) (стирол)2.
    Notes: Abstract The interaction of the cobalt phosphine complexes Co(N2)(PPh3)3, HCo(N2)(PPh3)3 and H3Co(PPh3)3 with styrene yields mono and dinuclear complexes identified by the ESR method. A paramagnetic complex, Co(PPh3) (styrene)2, is one of the intermediates in the catalytic hydrogenation of styrene.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02068909
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  • 3
    Electronic Resource
    Electronic Resource
    Influence of the various forms of molybdena on the adsorptive and catalytic (dehydrogenation and hydrogenolysis) properties of molybdena-alumina catalysts (1980)
    Springer
    Reaction kinetics and catalysis letters 14 (1980), S. 283-287 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract По растворимости в воде и аммиаке определены количества трёх форм окисных соединений молибдена в алюмомолибденовых катализаторах. Активной в реакции дегидрирования циклогексана является легко растворимая в воде форма, восстанавливающаяся при 400°C и PH 2=I ата до Mo(IV); а в гидрогенолизе тиофена —растворимые в воде и аммиаке формы соединений молибдена.
    Notes: Abstract The contents of three forms of molybdenum oxide compounds in molybdena-alumina catalysts have been determined by their solubility in water and ammonia. The form which is readily soluble in water and reducible to Mo(IV) at 400°C and PH2=105 Pa is active in cyclohexane dehydration, and the forms soluble in water and ammonia are active in thiophene hydrogenolysis.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02073492
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