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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters A 72 (1979), S. 225-228 
    ISSN: 0375-9601
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9567
    Keywords: gas-liquid phase equilibrium ; isochores ; triple point ; vapor pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract For the investigations of the gas-liquid phase equilibria, a new apparatus has been developed capable of simultaneously determining the pressure and the liquid and vapor densities using Archimedes' principle. The relative measurement uncertainties of the liquid and vapor densities of R134a (purity, 99.999%) at 313 K are 2×10−4 and 7×10−4, respectively (95% confidence level). For the measurements in the liquid region along nine quasi-isochores at pressures up to 5 MPa, an isochoric apparatus was used. The relative measurement uncertainty ofpv/(RT) is less than 1×10−3. In addition to the investigation of the (p, v, T) properties, the temperature and pressure at the triple point and the vapor pressure between the triple point and 265 K were measured. On the basis of these data, a vapor pressure correlation has been developed that reproduces the measured vapor pressures within the uncertainty of measurement. The results of our measurements are compared with a fundamental equation for R134a, which is based on the measurements of other research groups.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 19 (1998), S. 653-662 
    ISSN: 1572-9567
    Keywords: Clausius–Clapeyron equation ; enthalpy of vaporization ; R134a ; 1,1,1,1,2-tetrafluoroethane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An apparatus is described which is capable of measuring the enthalpy of vaporization in the temperature range from 100 to 250 K. The sample (R134a; purity, at least 99.999%) is located in the measuring cell at the saturated vapor pressure, p = p s. A control circuit allows p to be kept constant by opening a motor-operated valve to a weighing cylinder after having switched on the electrical measuring cell heater. During the experiment, the temperature is kept constant within a 10mK. In the range 180 to 230 K, the data for R134a are compared with calculated values from the fundamental equation given by Tillner-Roth and Baehr, which is recommended by Annex 18 of the International Energy Agency (IEA) as an international standard. Good agreement within a standard uncertainty of 1.6×10−3 is obtained. At temperatures of only 10 K above the triple-point temperature, the enthalpy of vaporization calculated from the Clausius–Clapeyron equation shows considerable uncertainty due to the determination of the small vapor pressure. It is chiefly in this range that it is advantageous to have the new apparatus.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 13 (1988), S. 183-185 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The sensitivity and hazard associated with the firing of monergolic liquid gun propellants is described in some detail taking a user oriented point of view. Emphasis is placed on the practical aspects encountered in the ignition and combustion of monopropellants in regenerative gun systems. This analysis is based upon experimental evidence obtained from compression ignition studies, closed bomb work and gun firings.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 10 (1985), S. 31-38 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The ignition and combustion behavior of both the 27-mm and 20-mm gun propellants Q5560 und A 5021 is identified from a series of detailed experiments conducted on a caliber 20-mm test fixture gun. A novel invasive technique is applied that permits propellant gas temperature to be evaluated from emission data taken at discrete axial locations within the 20-mm gun chamber. Supplementary pressure measurements complete the investigation. A correlation of the data obtained at the vent of the pyrotechnic igniter and inside the burning granular propellant bed is presented establishing quantitative relationships between the igniter energy output and the ignition behavior of the propellants.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 20 (1995), S. 225-231 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The present paper deals with pressure oscillations in regenerative liquid propellant guns (RLPG) presenting the state-of-the-art research into sources and control of these combustion instabilities. Pressure oscillations with amplitudes up to 50 % of mean pressure and frequencies up to 60 kHz or more are present in experimental data of RLPGs, especially at medium and large calibers. Amplitudes increase with the volumetric energy density of the liquid propellant and the mass flow rate during injection. Frequency analyses reveal that both acoustic modes and combustion noise are components of the recorded oscillations. Acoustic modes, in particular, have the potential to couple to resonant modes in near-field mechanical structures. A multi-phase, multi-dimensional model investigation at ARL indicates that pressure waves reflected from internal boundaries are amplified as they pass the combustion zone of the highly pressure-sensitive liquid propellant in a localized region near the injector. Experimental data lead to a similar understanding of the amplification of pressure oscillations in RLPGs. Experiments in the United States and in Germany confirm that the pressure oscillations can be mitigated by altering the combustion characteristics of the liquid propellant. Also, techniques that more effectively disperse the liquid propellant jet and thereby decrease the local accumulation of liquid propellant, may reduce pressure oscillations as shown in 30-mm RLPG experiments. Further, energy-absorb-ing chamber walls or liners can serve as broad-band filters and have been shown experimentally to be effective in reducing the amplitude of all frequencies. In addition, physical methods such as cavities and baffles reduce significantly specific acoustic frequencies of the oscillations.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 9 (1984), S. 91-107 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A special igniter case designed by Dynamit Nobel AG was used for measuring the energy output of four different igniter formulations in terms of gas pressure, flame temperature, and gas velocity in order to study the performance of pyrotechnic igniter systems, and to evaluate the energy flux at the igniter vent. Four igniter systems were defined which consisted of (a) B-KNO3, (b) black powder, (c) nitrocellulose, and (d) mixtures of nitrocellulose with black powder. Firings into open air, propellant dummy loads, and propellant beds were carried out with these igniters to obtain their general characteristics. It has been found that the vent characteristics of these pyrotechnic igniters are determined by the confinement conditions used. The energy flux at the igniters vent increased considerably for firings into inert or active propellant beds.
    Additional Material: 23 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 15 (1990), S. 103-114 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Progress achieved in the study of the electrical ignition of the hydroxylammonium nitrate(HAN)-based liquid gun propellant LGP 1846 is described. The goal of the work is to develop an igniter system suitable for regenerative liquid propellant guns. Several igniter configurations of the one- as well as the two-stage types designed by the Ballistic Research Laboratory and the Fraunhofer-Institut EMI-AFB, have been tested. Voltage and current as well as the pressure histories were recorded. Calculations of electrostatic field distributions discussed here were obtained by a finite element code implemented at Dynamit Nobel. The theoretical analysis yielded alternative electrode designs for future testing. In addition, a specially designed igniter chamber equipped with sapphire windows was used at EMJ-AFB to study the fundamentals of the electrical discharge by means of high-speed photography.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 20 (1995), S. 304-310 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Modern gun propulsion techniques are driven by the desire to increase muzzle kinetic energy as a means to enhance weapon lethality, reduce costs, increase reliability, and improve vulnerability. In recent years, a significant part of research and developmental activities has been focused not only on conventional solid-propellant and novel liquid-propellant gun propulsion techniques but also on advanced concepts, particularly those offering substantial performance increase. High performance can be achieved by pure electric systems(coil or rail gun) as well as by combining chemical propulsion either with gasdynamic principles (light gas gun or ram accelerator) or with electrothermal techniques (hybrid gun). Part I of this paper deals with the fundamentals of projectile acceleration techniques. The objective is to provide the basis for understanding gun technology and to lay the basis for assessing present and future developments.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 14 (1989), S. 57-68 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gun muzzle blast and flash phenomena are of importance since they are associated with the formation of large overpressures and intense muzzle flash. About 30% of the chemical energy released from the propellant used in a conventional gun is converted into kinetic energy of the projectile. The remaining energy is mainly contained in the propellant gas-particle mixture which escapes from the muzzle of the gun in a few milliseconds. The sudden discharge produces a blast wave because of the rapid displacement of air originally surrounding the gun. In addition, these gases are generally fuel-rich and mix with air turbulently entrained from the surroundings. Combustion of this mixture causes gun muzzle flash, usually associated with the formation of a secondary blast wave. The design of solid propellant charges, gun performance, muzzle attachments and chemical flash suppressants is guided by the need to keep the above hazards to safe limits. In this paper, blast and flash phenomena are characterized using data of recent investigations and showing illustrative examples of their development.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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