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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 7 (1915), S. 99-102 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 15 (1923), S. 745-746 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 10 (1973), S. 759-779 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A simple algebraic expression for the reversible magnetization curve in low-κ type-II superconductors is proposed. This model has been checked on the experimental results of very pure Nb and V, as measured by several authors. A quite good agreement is found forT/T c 〉0.4; for lower temperatures the agreement becomes worse, but this model still seems better than any other model known thus far from the literature. Using this relation together with a critical-state model it is possible to calculate the irreversible magnetization curves in increasing and decreasing fields betweenH c 1 andH Hc H2 . The results are compared with the experimental data we obtained on a rectangular Nb sample. It turns out that Goedemoed's pinning model gives a good description. Also, a method is described to obtain the flux density gradient as a function ofB directly from magnetization measurements. This provides a more sensitive method to compare the experiments with critical-state models.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 16 (1974), S. 169-191 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The effect of irradiation with fast neutrons (at reactor ambient temperatures up to doses of 1.5×1020 n/cm2) on the magnetic behavior in stationary fields of superconducting niobium samples has been studied. Surface effects have been removed by oxidation of the samples. Irradiation leads to an increase ofH c2, which disappears after annealing the samples at 400°C. Also, the irreversibility of the magnetization increases and a peak effect is induced in the magnetization curves. These effects, due to an increased bulk pinning, are rather small, except in the samples irradiated with the highest dose. Electron microscope pictures showed that this is due to the fact that only for the highest dose do the clusters of interstitials which are introduced in the sample by the irradiation form extended defects, with sizes larger than the coherence length ξ. A discussion is given of te surface barrier before and after irradiation, of theH c2 shift due to the irradiation, and of the increased irreversibility of the magnetization. It turns out that nearH c2 the irradiation damage has to be treated as line defects, rather than as point defects, whereas at lower fields neither the critical state formula of Labusch for point pinning nor that of Good and Kramer for line pinning describes the experimental results exactly, although the differences do not seem to be very dramatic. We conclude that in the lower field region a combination of point and line pinning occurs. The peak effect has been discussed in a foregoing paper.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 6 (1972), S. 1-33 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A number of simple models are discussed for the magnetic permeability behavior of type-II superconductors. It turns out that the London-Bean model extended with a surface barrier as discussed by Ullmaier and by Wipf, though it gives a satisfactory description of the alternating current losses, fails as soon as the real part of the permeability is also taken into account. It proves to be possible, however, to give a different extension to the London-Bean model consisting of a surface layer without pinning. This model is in satisfactory agreement with the experimental data.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 17 (1974), S. 295-322 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Alternating field permeability experiments are reported on superconducting niobium samples irradiated with fast neutrons at reactor ambient temperatures. The results are compared with theoretical predictions derived from several critical state models. Fundamental differences are observed, even when the static magnetization curves are described quite well by the same model. This leads to the conclusion that for small periodic movements of the flux lattice the vortices are not in the critical state.
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  • 7
    ISSN: 1573-5036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The objective of this field study was to determine early-season effects of N source, N, K, and P fertilization, and clipping (to simulate grazing) on potential tetany hazard of bromegrass (Bromus inermis L.) as indicated by the chemical composition of its forage. Tetany is a metabolic disorder of ruminants resulting from forage with low Mg availability. Chemical components considered in the forage were inorganic cations, organic acids, aconitate, and per cent total N/per cent total water soluble carbohydrate (N/TWSC). Differences between the sum (in meq/kg) of inorganic cations (Mg, Ca, K, and Na) and inorganic anions (Cl, NO3, H2PO4, and SO4) in forage were defined as the concentration of organic acids (C-A). Soil was Parshall fsl, a Pachic Haploboroll. Yields and chemical composition of oven-dried forage from previously unclipped and reclipped plots were determined at 3-week intervals beginning May 22 and June 12, respectively. A water budget was determined using soil-water and rainfall data. Forage yields were increased 2- to 3-fold by N fertilization with the NO3-N source generally outyielding the NH4-N source. A slight additional yield response to that obtained with N alone was obtained with K+P fertilization but not with K or P alone with or without N. Much less total forage was removed from reclipped plots than from unclipped plots. Forage Mg content was decreased only slightly by K or NH4-N fertilization. Soil analysis indicated that high NH4-N levels were present at the May 22 harvest. Magnesium and Ca concentrations were only slightly affected by N fertilization; however, K, K/(Ca+Mg), total N, C-A, and aconitate were increased. Reclipping increased Mg, N, K, N/TWSC, C-A, and aconitate. Estimates of blood-plasma Mg concentrations were obtained by using the data for plant N, K, and Mg. These estimates did not indicate increased tetany hazard as a result of reclipping, but did indicate increased tetany hazard from N fertilization. Forage C-A and aconitate concentrations were decreased by fertilization with KCl which seemed to have been caused by the increased Cl concentrations in the forage. Estimates of quantities of Mg, arriving at the root surfaces from the soil by mass flow, far exceeded amounts of Mg in the forage. Mass flow seemed to be the principal mechanism by which Mg and Ca arrived at root surfaces but this mechanism was much less important for K. This study indicated an increased potential tetany hazard resulting primarily from N fertilization with either NH4-N or NO3-N sources. However, the potential for increased forage and livestock-carrying capacity with N fertilization is very large. Therefore, management practices corroborated by livestock data are vitally needed to minimize tetany hazard while increasing bromegrass yields by N fertilization.
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  • 8
    ISSN: 1573-5036
    Keywords: cattle slurry ; denitrification ; grassland ; nitrification ; nitrification inhibitor ; slurry injection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Injection of cattle slurry into a grassland soil decreases NH3 volatilisation and increases N utilisation by the sward, but may also increase denitrification losses. Denitrification rates were measured using a soil core incubation technique involving acetylene inhibition, following injection of cattle slurry (67 t ha−1) into a grassland soil. The slurry was injected, either with or without a nitrification inhibitor (DCD), on 8 December 1989. Two-weekly measurements were carried out up to 18 weeks after injection. Compared to the control plot, denitrification rates were significantly higher after slurry injection. Addition of DCD to the slurry almost eliminated this effect. Estimated N-losses during 18 weeks after injection were 0.9 (control), 4.1 (+DCD), and 13.7 (-DCD) kg N ha−1. Denitrification losses were 7% of the injected NH4-N and decreased to 2% of the injected NH4-N when DCD was added. Denitrification could account for about 19% of the difference in apparent recovery of N from slurry injected with and without DCD. The results suggested that considerable amounts of NO3 − were lost due to leaching.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 163 (1994), S. 235-241 
    ISSN: 1573-5036
    Keywords: denitrification ; grassland ; nitrification ; nitrous oxide ; sandy soil ; urine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Denitrification and N2O emission rates were measured following two applications of artificial urine (40 g urine-N m−2) to a perennial rye-grass sward on sandy soil. To distinguish between N2O emission from denitrification or nitrification, urine was also applied with a nitrification inhibitor (dicyandiamide, DCD). During a 14 day period following each application, the soil was frequently sampled, and incubated with and without acetylene to measure denitrification and N2O emission rates, respectively. Urine application significantly increased denitrification and N2O emission rates up to 14 days after application, with rates amounting to 0.9 and 0.6 g N m−2 day−1 (9 and 6 kg N ha−1 day−1), respectively. When DCD was added to the urine, N2O emission rates were significantly lower from 3 to 7 days after urine application onwards. Denitrification was the main source of N2O immediately following each urine application. 14 days after the first application, when soil water contents dropped to 15% (v/v) N2O mainly derived from nitrification. Total denitrification losses during the 14 day periods were 7 g N m−2, or 18% of the urine-N applied. Total N2O emission losses were 6.5 and 3 g N m−2, or 16% and 8% of the urine-N applied for the two periods. The minimum estimations of denitrification and N2O emission losses from urine-affected soil were 45 to 55 kg N ha−1 year−1, and 20 to 50 kg N ha−1 year−1, respectively.
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  • 10
    ISSN: 1573-5036
    Keywords: acetylene ; denitrification ; fertilizer-N ; grazed grassland ; loam ; peat ; sand ; seasonal variation ; soil water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract During the growing season of 1989 and 1990 denitrification measurements were carried out in grazed perennial rye-grass swards on sand, loam and peat soils, each receiving two rates of nitrogen fertilizer. Denitrification was measured monthly, using a coring system with acetylene inhibition. Denitrification rates were highly variable throughout the season but tended to increase with increasing soil water content. High denitrification rates (0.1 kg N ha-1 day-1) were observed in spring and autumn, and were associated with rainfall or grazing in combination with a high soil water content. Estimated seasonal denitrification losses ranged between 1 and 21% of the fertilizer input, and showed no significant effect of fertilizer application rate. In 1990, denitrification losses were significantly higher on the loam soil. However, this difference was rather a result of different timing of sampling after rainfall or grazing, than of soil type differences. In the growing season of 1991, field experiments were carried out in the same sites, to measure denitrification losses during the first 8 or 10 days after fertilizer application. Fertilizer application significantly increased denitrification rates. Losses following one fertilizer application ranged from 6 to 9% of the fertilizer input, but only on a wet soil.
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