ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary 1. On reaction of 1,4-dichloro-2-butyne with aqueous-methanolic or methanolic potassium hydroxide the following products may be obtained, depending on the reaction conditions: 2-chloro-1-buten-3-yne, 2-chloro-4-methoxy-1,3-butadiene, butadiyne, 1-methoxy-1-buten-3-yne, and tetrolaldehyde dimethyl acetal. 2. A mechanism is proposed for the acetylene-allene-diene isomerization of 1,4-dichloro-2-butyne in aqueous-alcoholic and alcoholic solutions of potassium hydroxide.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00903981
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