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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 22 (2002), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, pose environmental threats to ground water resources worldwide. DNAPL site characterization method performance comparisons are presented in a companion paper (Kram et al. 2001). This study compares the costs for implementing various characterization approaches using synthetic unit model scenarios (UMSs), each with particular physical characteristics. Unit costs and assumptions related to labor, equipment, and consumables are applied to determine costs associated with each approach for various UMSs. In general, the direct-push sensor systems provide cost-effective characterization information in soils that are penetrable with relatively shallow (less than 10 to 15 m) water tables. For sites with impenetrable lithology using direct-push techniques, the Ribbon NAPL Sampler Flexible Liner Underground Technologies Everting (FLUTe) membrane appears to be the most cost-effective approach. For all scenarios studied, partitioning interwell tracer tests (PITTs) are the most expensive approach due to the extensive pre-and post-PITT requirements. However, the PITT is capable of providing useful additional information, such as approximate DNAPL saturation, which is not generally available from any of the other approaches included in this comparison.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 21 (2001), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: The site characterization and analysis cone penetrometer system (SCAPS), equipped with realtime fluorophore detection capabilities, was used to delineate subsurface contaminant releases in an area where plating shop waste was temporarily stored. Records indicated that various nonaqueous phase liquids (NAPLs) were released at the site. The investigators advanced the SCAPS laser-induced fluorescence (LIF) sensor to depths beneath the water table of the principal water-bearing zone. The water table was located approximately 6 feet (1.8 m) below ground surface (bgs) across the site. Fluorescence, attributed to fuel compounds commingled with chlorinated solvents, was observed at depths ranging from 4.0 to 11.5 feet (1.2 to 3.5 m) bgs. Fluorescence, attributed to naturally occurring organic materials (by process of elimination and spectral characteristics) commingled with chlorinated solvent constituents, was observed at depths ranging from approximately 13 to 40 feet (4.0 to 12.2 m) bgs. Fluorescence responses from compounds confirmed to be commingled with chlorinated solvents indicates that the SCAPS fluorophore detection system is capable of indirectly delineating vadose zone and subaqueous chlorinated solvents and other dense nonaqueous phase liquids (DNAPLs) at contaminant release sites. This confirmation effort represents the first documented account of the successful application of LIF to identify a mixed DNAPL/LNAPL source zone.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 21 (2001), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, represents an environmental challenge with global implications. Mass-transfer limitations due to rate-limited dissolution can lead to long-term aquifer persistence for even small volumetric fractions. The identification of DNAPL source zones located beneath the water table is critical to ultimately achieve site remediation and aquifer restoration. This paper provides a comparison of the advantages and disadvantages of many of the methods being used for detecting and delineating DNAPL contaminant source zones. The objective is to determine which options are best to pursue based on site characteristics, method performance, and method costs. DNAPL characterization methods are grouped into approaches, which include site preparation, characterization, and data-processing activities necessary to design an effective remediation system. We compare the different approaches based on the level of chemical and hydrogeologic resolution, and the need for additional data requirements. Our findings can be used to assist with selection of appropriate site remediation management options.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Treatment of methyl tertiary-butyl ether (MTBE) from contaminated surface and ground water supplies presents specific challenges due to the physicochemical properties of MTBE that depend strongly on its hydrophilic nature, and translate into a high solubility in water, and low Henry's constant and low affinity for common adsorbents. We evaluate four treatment technologies-air stripping, granular activated carbon (GAC), hydrophobic hollow fiber membranes, and advanced oxidation processes (AOP)-using ozone or ozone/hydrogen peroxide. Experimental work was carried out to generate parameter values necessary for the design of these processes. Ten different flow rates/concentration combinations were evaluated in our designs to cover the range from high flow rate/low concentration typical of surface water and ground water drinking water supplies to low flow rate/high concentration typical of ground water remediation sites. For all cases, the processes were designed to produce effluent water of 5 μg/L or less. Capital costs and operation and maintenance costs were determined at the feasibility level by using standard engineering estimating practices.Air stripping is the lowest cost technology for high flow rales (100 to 1000 gpm) if no air treatment is required. Hollow fiber membranes are the lowest cost technology for flow rates of 10 to 100 gpm if no air treatment is required, which is typical at these low flow rates. GAC will be most costeffective at all flow rates if air treatment is required and the influent water has low levels of other organic compounds. AOP using ozone or ozone/hydrogen peroxide is in all cases more expensive than the alternative technologies, and there are sufficient uncertainties at this point with respect to byproducts of AOP to warrant further study of this technology. The cost of treating MTBE-contaminated water for conventional technologies such as air stripping and GAC is 40% to 80% higher than treating water contaminated only with other hydrocarbons such as benzene.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 40 (2004), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : Traditional approaches to establishing critical water quality conditions, based on statistical analysis of low flow conditions and expressed as a recurrence interval for low flow conditions (e.g., 7Q10), may be inappropriate for drier watersheds. The use of 7Q10 as a standard design flow assumes year-round flow, but in these watersheds, 7Q10 is zero or very small. In addition, the increasing use of multiple year dynamic water quality models at daily time steps can supercede the use of steady state approaches. Many of these watersheds are also under increasing urbanization pressure, which accentuates the flashiness of runoff and the episodic nature of critical water quality conditions. To illustrate, the conditions in the Santa Clara River, California, are considered. A statistical analysis indicates that higher inorganic nitrogen concentrations correlate strongly with low flow. However, peaks in concentrations can occur during the first storms, particularly where nonpoint source contribution is significant. Critical conditions can thus occur at different flow regimes depending on the relative magnitude of flow and pollutant contributions from various sources. The use of steady state models for these dry semi-urbanized watersheds based on 7Q10 flows is thus unlikely to accurately simulate the potential for exceeding water quality objectives. Dynamic simulation of water quality is necessary, and as the recent intense storm event sampling data indicate, the models should be formulated to consider even smaller time steps. This places increasing demand on computational resources and datasets to accurately calibrate the models at this temporal resolution.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Environmental management 22 (1998), S. 757-766 
    ISSN: 1432-1009
    Keywords: KEY WORDS: Global carbon; Terrestrial storage; Carbon dioxide; Fossil fuel emissions; Drylands; Land degradation; Land restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Using estimates of land suitable for restoration in woodlands, grasslands, and deserts, as well as estimates of the rate at which restoration can proceed, we estimate that carbon storage in these biomes can range up to 0.8 billion tons of carbon per year (Gt C/yr), for a combination of land management strategies. This corresponds to a reduction in atmospheric buildup of 0.5 Gt C/yr, which represents up to 15% of the average annual atmospheric carbon buildup in the next century, 3.5 Gt C/yr, assuming the IPCC 92d scenario. A global strategy for reducing atmospheric carbon dioxide concentration will require the implementation of multiple options. The advantage of carbon storage in restored drylands is that it comes as a side benefit to programs that are also justifiable in terms of land management.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Climatic change 30 (1995), S. 367-395 
    ISSN: 1573-1480
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Using a global carbon cycle model (GLOCO) that considers seven terrestrial biomes, surface and deep ocean layers based on the HILDA model and a single mixed atmosphere, we analyzed the response of atmospheric CO2 concentration and oceanic DIC and DOC depth profiles to additions of carbon to the atmosphere and ocean. The rate of transport of carbon to the deepest oceanic layers is rather insensitive to the atmosphereic-ocean surface gas exchange coefficient over a wide range, hence discrepancies between researchers on the precise global average value of this coefficient do not significantly affect predictions of atmospheric response to anthropogenic inputs. Upwelling velocity, on the other hand, amplifies oceanic response by increasing primary production in the upper ocean layers, resulting in a larger flux into DOC and sediments and increased carbon storage; experiments to reduce the uncertainty in this parameter would be valuable. The location of the carbon addition, whether it is released in the atmosphere or in the middle of the oceanic thermocline, has a significant impact on the maximum atmospheric CO2 concentration (pCO2) subsequently reached, suggesting that oceanic burial of a significant fraction of carbon emissions (e.g. via clathrate hydrides) may be an important management option for limiting pCO2 buildup. Our analysis indicates that the effectiveness of ocean burial decreases asymptotically below about 1000 m depth. With a constant emissions scenario (at 1990 levels), pCO2 at year 2100 is reduced from 501 ppmv considering all emissions go to the atmosphere, to 422 ppmv with ocean burial at a depth of 1000 m of 50% of the fossil fuel emissions. An alternative scenario looks at stabilizing pCO2 at 450 ppmv; with no ocean burial of fossil fuel emissions, the rate of emissions has to be cut drastically after the year 2010, whereas oceanic burial of 2 GtC/yr allows for a smoother transition to alternative energy sources.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Climatic change 33 (1996), S. 63-68 
    ISSN: 1573-1480
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Transport in porous media 26 (1997), S. 277-297 
    ISSN: 1573-1634
    Keywords: NAPL ; multiphase flow ; three-phase flow ; film flow ; micromodel ; spreading coefficient ; non-spreading oil.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract We have studied the flow of a non-aqueous phase liquid (NAPL, or oil), water and air at the pore scale using a micromodel. The pore space pattern from a photomicrograph of a two-dimensional section through a Berea sandstone was etched onto a silicon wafer. The sizes of the pores in the micromodel are in the range 3–30,μm and are the same as observed in the rock from which the image was taken. We conducted three-phase displacement experiments at low capillary numbers (in the order of 10-7) to observe the presence of predicted displacement mechanisms at the pore scale. We observed stable oil layers between the wetting phase (water) and the non-wetting phase (gas) for the water–decane–air system, which has a negative equilibrium spreading coefficient, as well as four different types of double displacements where one fluid displaces another that displaces a third. Double imbibition and double drainage are readily observed, but the existence of an oil layer surrounding the gas phase makes the other double displacement combinations very unlikely.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Transport in porous media 38 (2000), S. 189-203 
    ISSN: 1573-1634
    Keywords: NAPL ; capillary pressure ; relative permeability ; network model ; multiphase flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract After dense nonaqueous phase liquids (DNAPLs) travel downward through the subsurface, they typically come to rest on fractured bedrock or tight clay layers, which become additional pathways for DNAPL migration. DNAPLs trapped in fractures are continuous sources of groundwater contamination. To decide whether they can be left in place to dissolve or volatilize, or must be removed with active treatment, the movement of DNAPLs in fractured media must be understood at a fundamental level. This work presents numerical simulations of the movements of DNAPLs in naturally fractured media under two‐phase flow conditions. The flow is modeled using a multiphase network flow model, used to develop predictive capabilities for DNAPL flow in fractures. Capillary pressure–saturation–relative permeability curves are developed for two‐phase flow in fractures. Comparisons are made between the behavior in crystalline, almost impermeable rocks (e.g. granite) and more permeable rocks like sandstone, to understand the effects of the rock matrix on the displacement of the DNAPLs in the fracture. For capillary‐dominated flow, displacements occur as a sequence of jumps, as the invading phase overcomes the capillary pressure at downgradient apertures. Preferential channels for the displacement of nonaqueous phase are formed due to high fracture aperture in some regions.
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