Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
87 (1987), S. 3321-3331
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
High-resolution laser photofragment spectroscopy of the 3s,3d←2p c 3Π−u transitions in HD has been performed in a fast mass and state-selected beam. Transition wave numbers and rotational energy levels are given for v=0–3 of the h3∑+g, g 3∑+g, i 3Πg, and j 3Δg states. The data are represented by an effective Hamiltonian which accounts for the rotational breakdown of the Born–Oppenheimer approximation (L-uncoupling). The model parameters indicate a vibrational Born–Oppenheimer breakdown in the i 3Πg state. Good agreement with the most accurate ab initio calculations is obtained.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.453026
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