Publication Date:
2014-11-11
Description:
Lead-free multiferroic ceramics of 0.75Bi 1−x Nd x FeO 3 − 0.25BaTiO 3 + 1 mol. % MnO 2 were prepared by a conventional ceramic technique and their structure, piezoelectricity, and multiferroicity were studied. The ceramics sintered at 890–990 °C possess a pure perovskite structure. A morphotropic phase boundary of rhombohedral and monoclinic phases is formed at x = 0.05. A small amount of Nd improves the ferroelectric and piezoelectric properties of the ceramics. The ferroelectric-paraelectric phase transition becomes gradually diffusive with x increasing. After the addition of Nd, the ferromagnetism of the ceramics is greatly enhanced by ∼320%. The increase in sintering temperature improves significantly the ferroelectric, piezoelectric, and ferromagnetic properties of the ceramics. The ceramics with x = 0.05 sintered at 950–990 °C possess improved ferroelectricity, piezoelectricity, magnetism and insulation with P r of 16.5–17.5 μ C/cm 2 , d 33 of 113–121 pC/N, M r of 0.127–0.138 emu/g, R of ∼5 × 10 9 Ω·cm and high T C of 473–482 °C, indicating that the ceramic is a promising candidate for room-temperature multiferroic and high-temperature piezoelectric materials.
Print ISSN:
0021-8979
Electronic ISSN:
1089-7550
Topics:
Physics
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