ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
This paper describes the synthesis, physical properties, and the impact modification of poly(N-phenylnorbornene dicarboximide) (PNDI). Impact modification is carried out both by physical blending with acrylonitrile-butadiene rubber (Hycar®) and by in situ metathesis polymerization of the monomer with the rubber. Better success is achieved by in situ metathesis polymerization. A copolymer, poly(N-phenylnorbornene dicarboximide) - co-poly(norbornene nitrile) containing Hycar rubber (PNDI/PNN/Hycar), is prepared with a good balance of high-heat impact and flexural properties. The melt viscoelastic behavior of PNDI/PNN/Hycar is evaluated and the energy of activation for viscous flow (Ea) was found to be 42 kcal/mol. © 1993 John Wiley & Sons, Inc.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1993.070501007
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