Publication Date:
2008-09-27
Description:
The detailed chemical structure of graphite oxide (GO), a layered material prepared from graphite almost 150 years ago and a precursor to chemically modified graphenes, has not been previously resolved because of the pseudo-random chemical functionalization of each layer, as well as variations in exact composition. Carbon-13 (13C) solid-state nuclear magnetic resonance (SSNMR) spectra of GO for natural abundance 13C have poor signal-to-noise ratios. Approximately 100% 13C-labeled graphite was made and converted to 13C-labeled GO, and 13C SSNMR was used to reveal details of the chemical bonding network, including the chemical groups and their connections. Carbon-13-labeled graphite can be used to prepare chemically modified graphenes for 13C SSNMR analysis with enhanced sensitivity and for fundamental studies of 13C-labeled graphite and graphene.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Cai, Weiwei -- Piner, Richard D -- Stadermann, Frank J -- Park, Sungjin -- Shaibat, Medhat A -- Ishii, Yoshitaka -- Yang, Dongxing -- Velamakanni, Aruna -- An, Sung Jin -- Stoller, Meryl -- An, Jinho -- Chen, Dongmin -- Ruoff, Rodney S -- New York, N.Y. -- Science. 2008 Sep 26;321(5897):1815-7. doi: 10.1126/science.1162369.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Mechanical Engineering and the Texas Materials Institute, University of Texas at Austin, Austin, TX 78712, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/18818353" target="_blank"〉PubMed〈/a〉
Print ISSN:
0036-8075
Electronic ISSN:
1095-9203
Topics:
Biology
,
Chemistry and Pharmacology
,
Computer Science
,
Medicine
,
Natural Sciences in General
,
Physics
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