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  • 1
    Publication Date: 1974-05-01
    Print ISSN: 0022-3654
    Electronic ISSN: 1541-5740
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 1971-04-01
    Print ISSN: 0022-3654
    Electronic ISSN: 1541-5740
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 75 (1971), S. 1240-1246 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 78 (1974), S. 1078-1082 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of polymers and the environment 7 (1999), S. 197-201 
    ISSN: 1572-8900
    Keywords: Biodegradation ; biodegraded surface ; biodegradation in several media
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Biodegradable polymers generally decompose in the various media in our environments. These environments contain soils, seawater, and activated sludge. If biodegradable materials waste is discarded, they decompose in these media. The biodegradation process of biodegradable polymers was investigated by scanning electron microscopy. Polycaprolactone, polybutylene succinate, and P(3HB-co-3HV) were tested. The shapes of holes on the decomposing surfaces are different according to the biodegradation media. Semispherical holes are observed on the surfaces of polybutylene succinate films degraded in activated sludge and cracks are observed on the surfaces of polycaprolactone films degraded in soil.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 3107-3114 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyethylene films were evaporated in gas plasmas of Ar, N2, O2, and H2O. The deposits were analyzed by infrared (IR) spectroscopy to determine the concentration of characteristic functional groups. The deposit prepared in Ar-atmosphere had a rather high concentration of methyl group and many double bonds were produced in the film. The deposits prepared in Ar- and N2-plasmas produced similar spectra, which showed twice the concentration of methyl group than the deposit in Ar-atmosphere and also contained a few carbonyl and hydroxyl groups. The film treated in O2-plasma contained the largest amount of carbonyl group and the lowest number of double bonds among the plasma-treated deposits. Dielectric loss curves against temperature for the deposits treated in these plasmas showed a broad peak near 20°C. For O2-plasma-treated film the loss tangent curves showed a sharp maximum. The activation energy for the relaxation of Ar-, O2-, and H2O-plasma-treated films had the same value of 50.6 kcal/mol. The observed relaxation in the films prepared in gas plasmas was considered due to the β process and was attributed to the motion of oxidized branched polyethylene.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 3457-3467 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dielectric constants and losses of four kinds of acrylonitrile-butadiene copolymers of different degrees of polymerization were measured in the glass-rubber transition region. Curves of the dielectric losses against frequency showed asymmetric loss curves as often seen in α-relaxations of polar polymers. The loci of Cole-Cole plots of the complex dielectric constants of these copolymers fitted well the loci of Havriliak-Negami's equation, \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm \varepsilon }^{\rm *} {\rm - \varepsilon }_\infty {\rm = (\varepsilon }_{\rm 0} {\rm - \varepsilon }_\infty {\rm )[1 + (j\omega T0)}^{{\rm 1 - \alpha }} {\rm ]}^{{\rm - \beta }} $$\end{document} The distribution parameters (1 - α) and β of the relaxation times were calculated. It is suggested that the mechanism of relaxation of the long chains is governed by a cooperative mechanism consisting of two concurrent motions: the first motion is the segmental relaxation of the polar chains, and the second is the induced motion of the neighboring segments successive to the first one.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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