ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A fragmentation reaction can be induced by generating a γ-amino-carbonium ion through a Wagner-Meerwein rearrangement of a δ-amino-p-toluenesulfonic ester. Thus solvolysis of 4-tosyloxymethyl-quinuclidine (9a) in aqueous ethanol yields the 4-methylene-1-aza-cycloheptanes (20a) and (20b).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19620450613
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