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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of agricultural and food chemistry 29 (1981), S. 675-677 
    ISSN: 1520-5118
    Source: ACS Legacy Archives
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Freshwater biology 12 (1982), S. 0 
    ISSN: 1365-2427
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: SUMMARY. Soluble reactive phosphorus (SRP) mass balances showed that phosphorus retention occurred during low summer flows in reaches of Duffin Creek and the Nottawasaga River, two phosphorus-rich streams in southern Ontario. The average daily removal in Duffin Creek was 6.1 ± 1.6 kg SRP which represents the retention of about 92% of the phosphorus input. Approximately 5.3 ± 3.5 kg SRP (about 44% of the daily input) was removed from stream water in the Nottawasaga River. Laboratory experiments indicate that sorption by stream-bed sediments is an important mechanism for phosphorus retention in both rivers. Uptake by benthic algae may also act as a temporary phosphorus sink in Duffin Creek. Major cation inputs and outputs are generally in balance, implying that these elements act in a relatively conservative manner in both rivers.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 17 (1981), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : The export of dissolved molybdate reactive phosphorus (DMRP) from 22 watersheds in the Duffin Creek drainage basin near Toronto Ontario was measured over a 25-month period. The annual average loss varied from 0.027 to 2.11 kg P/ha. Phosphorus levels in a number of watersheds were strongly influenced by effluent from a sewage treatment plant which contributed about 68 percent of the annual DMRP input to Duffin Creek. An analysis of 12 watersheds which did not contain major point pollution sources revealed that DMRP concentration and losses had a significant positive correlation with crop area and a strong negative association with forest, abandoned farm land, and area of sand + sandy loam soils. The causal relationships underlying these simple correlations are difficult to evaluate because of considerable multicollinearity between land use, soil, and topographic variables. Analysis of a mass balance for the downstream reaches of Duffin Creek indicated that there was considerable retention of phosphorus in the river channel particularly during summer low flows.
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  • 4
    ISSN: 1573-515X
    Keywords: ammonium ; groundwater ; hydrologic exchange ; hyporheic zone ; nitrate ; streams
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The influence of riffle-pool units on hyporheic zone hydrology and nitrogen dynamics was investigated in Brougham Creek, a N-rich agricultural stream in Ontario, Canada. Subsurface hydraulic gradients, differences in background stream and groundwater concentrations of conservative ions, and the movement of a bromide tracer indicated the downwelling of stream water at the head of riffles and upwelling in riffle-pool transitions under base flow conditions. Channel water also flowed laterally into the floodplain at the upstream end of riffles and followed a subsurface concentric flow path for distances of up to 20 m before returning to the stream at the transition from riffles to pools. Differences in observed vs predicted concentrations based on background chloride patterns indicated that the hyporheic zone was a sink for nitrate and a source for ammonium. The removal of nitrate in the streambed was confirmed by the loss of nitrate in relation to co-injected bromide in areas of downwelling stream water in two riffles. Average stream water nitrate-N concentrations of 1.0 mg/L were often depleted to 〈0.005 mg/L near the sediment-water interface. Consequently, an extensive volume of the hyporheic zone in the streambed and floodplain had a large unused potential for nitrate removal. Conceptual models based mainly on studies of streams with low nutrient concentrations have emphasized the extent of surface-subsurface exchanges and water residence times in the hyporheic zone as important controls on stream nutrient retention. In contrast, we suggest that nitrate retention in N-rich streams is influenced more by the size of surface water storage zones which increase the residence time of channel water in contact with the major sites of rapid nitrate depletion adjacent to the sediment-water interface.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 20 (1993), S. 19-44 
    ISSN: 1573-515X
    Keywords: ammonium ; nitrate ; riparian zone ; stream chemistry ; storm runoff ; swamp
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The influence of storm runoff processes on stream nitrogen dynamics was investigated in a headwater riparian swamp on the Oak Ridges moraine in southern Ontario. Hydrologic data were combined with analysis of an isotopic tracer (180) and nitrogen (NH 4 + , NO 3 − ) concentrations in saturation overland flow and stream discharge. Storm runoff was separated into its event and pre-event components using18O in order to examine the effect of water source on nitrogen chemistry. Laboratory experiments were also used to study nitrogen transformation associated with storm runoff-surface substrate interactions in the swamp. In most storms N03-N and NH4-N concentrations in the initial 3–4 mm throughfall increment were 10–20x and 20–100x higher respectively than stream base flow concentrations. Maximum stream N03-N concentrations were 〈 2x to 6x higher than base flow concentrations and preceded or coincided with peak stream discharge. Storm-to-storm variations in stream N03-N behaviour also occurred during the hydrograph recession phase. NH4-N concentrations attained an initial peak on the rising hydrograph limb, or at peak stream discharge. A second NH4-N increase occurred during the late recession phase 3–5 h after maximum stream discharge. Inorganic-N concentrations in surface runoff were similar to peak streamflow. The close agreement between observed N03-N concentrations and values predicted from a chemical mixing model indicate that stream N03-N variations were controlled mainly by the mixture of throughfall and groundwater in surface stormflow from the swamp. Laboratory experiments also indicated that N03-N in surface runoff behaved conservatively when mixed with swamp substrates. With the exception of the late hydrograph recession phase, observed stream NH4-N concentrations were much lower than concentrations predicted by the chemical mixing model. The rapid loss of NH4-N from mixtures of surface stormflow and swamp substrates in laboratory experiments and the absence of uptake in sterilized substrates indicated that NH4-N retention in surface storm runoff was due to biotic processes.
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  • 6
    ISSN: 1573-515X
    Keywords: denitrification ; groundwater ; nitrate ; organic carbon ; riparian zone ; sand aquifer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The influence of hydrology andpatterns of supply of electron donors and acceptors onsubsurface denitrification was studied in a forestriparian zone along the Boyne River in southernOntario that received high nitrogen inputs from a sandaquifer. Two hypotheses were tested: (1) subsurfacedenitrification is restricted to localized zones ofhigh activity; (2) denitrification zones occur atsites where groundwater flow paths transportNO3 − to supplies of available organiccarbon. A plume of nitrate-rich groundwater withconcentrations of 10–30 mg N L−1 flowed laterallyat depths of 1.5–5 m in sands beneath peat for ahorizontal distance of 100–140 m across the riparianzone to within 30–50 m of the river. In situ acetyleneinjections to piezometers revealed that significantdenitrification was restricted to a narrow zone ofsteep NO3 − and N2O decline at theplume margins. The location of these denitrificationsites in areas with steep gradients of groundwater DOCincrease supported hypothesis 2. Many of thesedenitrification “hotspots” occurred near interfacesbetween sands and either peats or buried river channeldeposits. Field experiments involving in situadditions of either glucose or NO3 − topiezometers indicated that denitrification wasC-limited in a large subsurface area of the riparianzone, and became N-limited beyond the narrow zone ofNO3 − consumption. These data suggest thatdenitrification may not effectively removeNO3 − from groundwater transported at depththrough permeable riparian sediments unlessinteraction occurs with localized supplies of organicmatter.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-515X
    Keywords: nitrogen mineralization ; nitrate ; nitrification ; soil water ; ground water ; streams
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Spatial variations in soil processes regulating mineral N losses to streams were studied in a small watershed near Toronto, Ontario. Annual net N mineralization in the 0–8 cm soil was measured in adjacent upland and riparian forest stands using in situ soil incubations from April 1985 to 1987. Mean annual rates of soil N mineralization and nitrification were higher in a maple soil (93.8 and 87.0 kg.ha−1) than in a pine soil (23.3 and 8.2 kg.ha−1 ). Very low mean rates of mineralization (3.3 kg.ha−1) and nitrification (3.4 kg.ha−1) were found in a riparian hemlock stand. Average NO3-N concentrations in soil solutions were 0.3–1.0 mg.L−1 in the maple stand and 〉0.06mg.L−1 in the pine stand. Concentrations of NO3−N in shallow ground water and stream water were 3–4× greater in a maple subwatershed than in a pine subwatershed. Rapid N uptake by vegetation was an important mechanism reducing solution losses of NO3−N in the maple stand. Low rates of nitrification were mainly responsible for negligible NO3−N solution losses in the pine stand.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Biodegradation 14 (1991), S. 209-224 
    ISSN: 1572-9729
    Keywords: ground water ; hydrology ; nitrogen ; mass balance ; nutrient retention ; swamp
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Ground water inputs and outputs of N were studied for a small ground water discharge swamp situated in a headwater drainage basin in southern Ontario, Canada. Darcy's equation with data for piezometers was used to measure inputs of shallow local ground water at the swamp margin and deep regional ground water beneath the swamp. Ground water flux was also quantified by measuring ground water discharge to the outlet stream draining the swamp in combination with a chemical mixing model to separate shallow and deep ground water components based on chloride differences. Estimates of shallow ground water flux determined by these two approaches agreed closely however, the piezometer data seriously underestimated the deep ground water input to the swamp. An average ground water input-output budget of total N (TN) total organic nitrogen (TON) ammonium (NH4 +-N) and nitrate (NO3 --N) was estimated for stream base flow periods which occurred on an average of 328 days each year during 1986–1990. Approximately 90% of the annual NO3 --N input was contributed by shallow ground water at the swamp margin. Deep ground water represented about 65% of the total ground water input and a similar proportion of TON and NH4 +-N inputs. Annual ground water NO3 --N inputs and outputs were similar whereas NH4 +-N retention was 4 kg ha-1 representing about 68% of annual ground water input. Annual TON inputs in ground water exceeded outputs by 7.7 kg ha (27%). The capacity of the swamp to regulate ground water N fluxes was influenced by the N chemistry of ground water inputs and the hydrologic pathways of transport within the swamp.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 206 (1990), S. 39-52 
    ISSN: 1573-5117
    Keywords: ammonium ; biogeochemistry ; denitrification ; ground water ; hydrologic flow paths ; nitrate ; riparian zone ; stream
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Interactions between ground water flow paths and water chemistry were studied in the riparian zone of a small headwater catchment near Toronto, Ontario. Significant variations in oxygen — 18 and chloride indicated the presence of distinct sources of water in the ground water flow system entering the near-stream zone. Shallow ground water at the upland perimeter of the riparian zone had nitrate-N, chloride and dissolved oxygen concentrations which ranged between 100–180 µg L−1, 1.2–1.8 mg L−1 and 4.6–9.1 mg L−1 respectively. Concentrations of nitrate — N in deep ground water flowing upward beneath the riparian wetland were 〈 10 µg L−1, whereas chloride and dissolved oxygen ranged between 0.6–0.9 mg L−1 and 0.4–2.2 mg L−1 respectively. Ammonium — N concentrations (20–60 µg L−1) were similar in shallow and deep ground water. Ground water was transported through the wetland to the stream by three hydrologic pathways. 1) Shallow ground water emerged as springs near the base of the hillslope producing surface rivulets which crossed the riparian zone to the stream. 2) Deep ground water flowed upward through organic soils and entered the rivulets within the wetland. 3) Deep ground water reached the stream as bed and bank seepage. Springs were higher in nitrate and chloride than rivulets entering the stream, whereas bank seeps had lower concentrations of nitrate and chloride and considerably higher ammonium concentrations than the rivulets. These contrasts in nitrate and chloride concentrations were related to initial differences in the ion chemistry of shallow and deep ground water rather than to element transformations within the riparian wetland. Differences in ammonium concentration between seeps and rivulets were caused by immobilization of ammonium in the substrates of aerobic rivulets, whereas little ammonium depletion probably occurred in deep ground water flowing upward through reduced subsurface organic soils around the stream perimeter.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 160 (1988), S. 111-122 
    ISSN: 1573-5117
    Keywords: denitrification ; mass balance ; nitrogen ; streams ; water residence time ; water temperature
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A mass balance procedure was used to analyze rates of nitrate depletion in three adjacent reaches of West Duffin Creek, Ontario, Canada. Daily nitrate losses in individual reaches were highly variable (0.5–24 kg N) during low and moderate stream flows in May–October, 1982–1985. Nitrate removal efficiency (nitrate loss as a % of nitrate input) showed a rapid exponential decline with increased nitrate inputs to each reach. Nitrate losses and nitrate removal efficiency also had a significant negative correlation with stream discharge. The association of large nitrate loads with high stream discharge reduced the nitrate removal capacity of the stream because of shorter residence times and a higher ratio of water volume to stream bed area. Water temperature exhibited a significant positive correlation with nitrate loss which may reflect increased denitrification at higher temperatures. Variations in nitrate losses and nitrate removal efficiency between the three reaches were highly influenced by differences in water residence time. Standarized nitrate losses with respect to water residence time revealed a longitudinal decline in nitrate depletion between the reaches which was associated with a downstream decrease in stream nitrate concentration and in the organic carbon content of fine textured sediments from pool habitats.
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