ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Metal Complexes of Phosphinic Acids, VII. Thio- and Selenophosphinates of VanadiumThe reaction of the phosphinic acid anions L=R2P(X)Y- (R=C2H5, C3H7; X, Y=S, Se) with VCl3 and VOSO4 yields complexes of the type VL3 and VOL2, the properties and electronic spectra of which are discussed. The complexes VOL2 tend to form adducts with donor solvents. The crystalline adduct VOL2·py (L=(C2H5)2P(S)S-; py=Pyridin) could be isolated.
Notes:
Die Umsetzung der Phosphinsäure-Anionen L=R2P(X)Y- (R=C2H5, C3H7; X, Y=S, Se) mit VCl3 und VOSO4 führt zu Komplexen des Typs VL3 und VOL2, deren Eigenschaften und Elektronenspektren diskutiert werden. Die Komplexe VOL2 neigen zur Adduktbildung mit Donatorsolventien. Kristallines VOL2·py (L=(C2H5)2P(S)S-; Py · Pyridin) konnte isoliert werden.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19711040607
Permalink
