ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
A solid/liquid separation process based on the transfer of hydrophobic coated mineral particles from a hydrocarbon to an aqueous phase is described. This process could be used, for example, to remove mineral matter from coal derived liquids in order to meet fuel specifications. A model system which involves hydrophobic, asphaltic, coated mineral matter particles in a model liquid, xylene, was used in conjunction with the mechanistic studies. The mineral matter distribution coefficient to the aqueous phase decreases rather than increases with time in batch experiments. Five asymptotic models based on the fate of the surface active chemical at long time are investigated. Included were adsorption on the mineral matter particle, adsorption at the oil/water interface, distribution of the surfactant to the aqueous phase, complete detergency, and partial detergency. Experimental data on the influence of surfactant concentration, contact time, water/oil ratio, and shear are consistent only with the partial detergency model.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690240504
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