ISSN:
1052-9306
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The mass spectrometric behaviour of maleimycin, a bicyclic maleimide antibiotic, is discussed in detail with the aid of exact mass measurements, metastables (linked scans B/E and B2/E), ionization and appearance energy measurements and deuterium labelling experiments. The unusual loss of NH3 from the molecular ion is highlighted and a possible mechanism is proposed.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/bms.1200080405
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